A Battery Powered Future: The Rise of Lithium-ion batteries and what it means for sustainability efforts

As we collectively move towards a greener future in which the shift to sustainable energy solutions have become a core global socio-political issue, lithium-ion batteries have come centre stage as a possible solution. Thanks to their ability to store large amounts of energy in a comparatively lightweight and compact form, they have revolutionised everything from consumer wearables to electric vehicles. But to what extent is a battery-powered future truly the perfect energy solution we’ve been looking for?

Facilitating greener energy opportunities

The rise in lithium-ion batteries comes with a plethora of advantages as we shift away from fossil fuel dependence, contributing to significant reductions in greenhouse gas emissions and air pollution. Particularly in relation to the electrification of transportation through electric vehicles (EVs). By powering EVs with clean electricity stored in batteries, the transportation sector can reduce its reliance on fossil fuels and decrease emissions of greenhouse gases and pollutants. As the EV sector becomes more competitive, and with many governments incentivising the rise of EVs, battery technology advancements continue to improve the range, charging speed, and affordability of EVs, accelerating their adoption and further reducing reliance on internal combustion engine vehicles.

Lithium-ion batteries also play an increasingly crucial role in stabilising power grids, allowing the integration of intermittent renewable energy sources, such as solar and wind power, into the electricity grid. The sun doesn’t always shine and it’s not always windy – but by storing excess energy generated during periods of high production and discharging it when needed, batteries facilitate a reliable supply of clean energy in a reliable, stable way which had previously been difficult to achieve. By optimising energy management and reducing losses associated with traditional energy systems, batteries contribute to more efficient and sustainable energy use across various sectors.

Just how green are lithium-ion batteries?

However, the increasing prevalence of batteries has come with its own set of environmental implications. The extraction and processing of the rare earth metals such as lithium and cobalt are often conducted under exploitative conditions in mining regions, and the extraction process can also have significant environmental impacts, including habitat destruction and water pollution. Furthermore, the disposal of lithium-ion batteries at the end of their life cycle also poses concerns about recycling and the potential for hazardous waste to leak into the environment.

However, there is another area of concern with lithium-ion batteries which, with their increased usage, has led to a rise in dangerous incidents: their volatile and combustible nature. Anyone who has seen thermal runaway of lithium-ion batteries cannot fail to recognise the risk attached to their increased use. Even the failure of small-scale lithium-ion consumer electronic device can cause deadly and devastating explosions and fires, which makes the storage and use of batteries on a larger scale in need of robust safety measures.

Risk management with lithium-ion batteries

Fortunately, there are ways of mitigating the risk attached to lithium-ion batteries. Commonly, Battery Management Systems (BMS) are used to monitor battery charge level, voltage, current and temperature- which can help identify issues with any batteries. However there is a more efficient and reliable way of detecting thermal runaway: gas detection.

Ahead of thermal runaway, the batteries undergo a process of ‘off-gassing’, in which increased quantities of toxic VOCs are released. By monitoring the gasses around the batteries, and signs of stress or damage can be identified before thermal runaway begins.

At present, many insurers focus on the risk of fire, encouraging Battery Energy Storage Systems (BESS) to have processes in place to ensure fires can be controlled and managed as quickly and effectively as possible. However, as lithium-ion batteries are highly sensitive to temperature, once a fire has begun in one battery, it is likely any other batteries in proximity will also be irrevocably damaged- or begin thermal runaway themselves. The solution is simple: identify the problems at the earliest possible stage through gas detection, and ensure fires can’t start in the first place to more robustly safeguard against disaster. 

You can’t put a price on safety

The cost attached to investing in sophisticated gas detection is negligible in contrast with the cost of fire – roughly 0.01% of the cost of a new project – making it an obvious choice for those seeking to mitigate risk with manufacturing, storing and using lithium-ion batteries. The damage to the property, cost to human health (and even life), alongside the harm caused to the natural environment with potential contamination issues following battery failure are all extensive and significant. Combined with the threat to maintaining a business on top of the damage control required, the need to avoid complicated and expensive clean-up operations is paramount. This is something the Crowcon team understand better than anyone.

Crowcon will work closely with you to ensure your business and personnel are as safe and secure as possible through cutting-edge gas detection technology, such as the MPS™ sensor. Our Molecular Property Spectrometer™ (MPS™) technology accurately detects over 15 hazardous gases in one, allowing for a higher standard of flammable gas detection and greater confidence in your battery safety.

Click here to speak to us about safeguarding your business

While realising the full potential of lithium-ion technology still requires addressing the environmental and social challenges associated with its production, maintenance and disposal, the increasing prevalence of lithium-ion batteries represents a significant step towards a more sustainable and cleaner energy future. Innovation in the maintenance and enhanced efficiency of renewable energy technologies, such as rechargeable batteries, is a crucial step in detaching society from dependence on fossil fuels. From powering our everyday devices to driving the transition to electric transportation and renewable energy, lithium-ion batteries are at the forefront of the sustainability revolution – and the Crowcon team are on hand to help make a greener and safer future for generations to come.

For more information on battery safety, download our eBook ‘The Battery Boom: The Explosive Rise of Thermal Runaway and how you can prevent it’.

Get your FREE copy of ‘The Battery Boom’ eBook

Want to know more about how Crowcon can help safeguard your business’ future with premier gas detection systems? Click here to get in touch for an obligation-free chat with a member of our team.

Molecular Property Spectrometer™ Flammable Gas Sensors

Developed by NevadaNano, Molecular Property Spectrometer™ (MPS™) sensors represent the next generation of flammable gas detectors. MPS™ can quickly detect over 15 characterised flammable gases at once. Until recently, anyone who needed to monitor flammable gases had to select either a traditional flammable gas detector containing a pellistor sensor calibrated for a specific gas, or containing an infra-red (IR) sensor which also varies in output according to the flammable gas being measured, and hence needs to be calibrated for each gas. While these remain beneficial solutions, they are not always ideal. For example, both sensor types require regular calibration and the catalytic pellistor sensors also need frequent bump testing to ensure they have not been damaged by contaminants (known as ‘sensor poisoning’ agents) or by harsh conditions. In some environments, sensors must frequently be changed, which is costly in terms of both money and downtime, or product availability. IR technology cannot detect hydrogen – which has no IR signature, and both IR and pellistor detectors sometimes incidentally detect other (i.e., non-calibrated) gases, giving inaccurate readings that may trigger false alarms or concern operators.  

Building on over 50 years of gas expertise, Crowcon is pioneering advanced MPS™ sensor technology that detects and accurately identifies over 15 different flammable gases in one device. Now available in Crowcon’s flagship Xgard Bright fixed detector and portable detectors Gasman and T4x. 

Benefits of Molecular Property Spectrometer™ Flammable Gas Sensors 

The MPS™ sensor delivers key features that provide real world tangible benefits to operator and hence workers. These include:  

No calibration 

When implementing a system containing a fixed head detector, it is common practice to service on a recommended schedule defined by manufacturer. This entails ongoing regular costs as well potentially disrupting production or process in order service or even gain access to detector or multiple detectors. There may also be a risk to personnel when detectors are mounted in particularly hazardous environments. Interaction with an MPS sensor is less stringent because there are no unrevealed failure modes, provided air is present. It would be wrong to say there is no calibration requirement. One factory calibration, followed by a gas test when commissioning is sufficient, because there is an internal automated calibration being performed every 2 seconds throughout the working life of the sensor. What is really meant is – no customer calibration.  

Multi species gas – ‘True LEL’™ 

Many industries and applications use or have as a by-product multiple gases within the same environment. This can be challenging for traditional sensor technology which can detect only a single gas that they were calibrated for at the correct level and can result in inaccurate reading and even false alarms which can halt process or production if another flammable gas type is present. The lack of response or over response frequently faced in multi gas environments can be frustrating and counterproductive compromising safety of best user practices. The MPS™ sensor can accurately detect multiple gases at once and instantly identify gas type. Additionally, the MPS™ sensor has a on board environmental compensation and does not require an externally applied correctional factor. Inaccurate readings and false alarms are a thing of the past. 

No sensor poisoning 

In certain environments traditional sensor types can be under risk of poisoning. Extreme pressure, temperature, and humidity all have the potential to damage sensors whist environmental toxins and contaminants can ‘poison’ sensors, leading to severely compromised performance. Detectors in environments where poisons or inhibitors may be encountered, regular and frequent testing is the only way to ensure that performance is not being degraded. Sensor failure due to poisoning can be a costly experience. The technology in the MPS™ sensor is not affected by contaminates in the environment. Processes that have contaminates now have access to a solution that operates reliably with fail safe design to alert operator to offer a peace of mind for personnel and assets located in hazardous environment. Additionally, the MPS sensor is not harmed by elevated flammable gas concentrations, which may cause cracking in conventional catalytic sensor types for example. The MPS sensor carries on working.  

Hydrogen (H2) 

The usage of Hydrogen in industrial processes is increasing as the focus to find a cleaner alternative to natural gas usage. Detection of Hydrogen is currently restricted to pellistor, metal oxide semiconductor, electrochemical and less accurate thermal conductivity sensor technology due to Infra-Red sensors inability to detect Hydrogen. When faced with challenges highlighted above in poisoning or false alarms, the current solution can leave operator with frequent bump testing and servicing in addition to false alarm challenges. The MPS™ sensor provides a far better solution for Hydrogen detection, removing the challenges faced with traditional sensor technology. A long-life, relatively fast responding hydrogen sensor that does not require calibration throughout the life cycle of the sensor, without the risk of poisoning or false alarms, can significantly save on total cost of ownership and reduces interaction with unit resulting in peace of mind and reduced risk for operators leveraging MPS™ technology. All of this is possible thanks to MPS™ technology, which is the biggest breakthrough in gas detection for several decades.  

How does the Molecular Property Spectrometer™ Flammable Gas Sensor work 

A micro-electromechanical system (MEMS) transducer—comprising an inert, micrometer-scale membrane with an embedded heater and thermometer—measures changes in the thermal properties of the air and gases in its proximity. Multiple measurements, akin to a thermal “spectrum,” as well as environmental data are processed to classify the type and concentration of flammable gas(es) present, including gas mixtures. This is called  TrueLEL. 

  1. Gas rapidly defuses through the sensor’s mesh screen and into the sensor chamber, entering the MEMS sensor module.​ 
  2. The joule heater rapidly heats the hot plate.​ 
  3. Real-time environmental conditions (temperature, pressure and humidity) are measured by the integrated environmental sensor.  
  4. The energy required to heat the sample is precisely measured using a resistance thermometer.​ 
  5. The gas level, corrected for gas category and environmental  conditions, is calculated and output to the gas detector. 

MPS in our Products 

Xgard Bright

Many industries and applications use or have as a by-product multiple gases within the same environment. This can be challenging for traditional sensor technology which can detect only a single gas that they were calibrated for at the correct level and can result in inaccurate reading. 

Xgard Bright with MPS™ sensor technology provides a ‘TrueLEL™’reading for all flammable gases in any multi species environment without requiring calibrationor scheduled maintenance over its 5-year+ lifecycle, reducing interruptions to your operations and increases up-time. This in turn reduces the interaction with the detector resulting in a lower total cost of ownership over the sensor life cycle and reduced risk to personnel and production output to complete regular maintenance. Xgard Bright MPS™ is tailor-made for Hydrogen detection, with the MPS™ sensor, only one device is needed saving space without compromising on safety. 

Gasman

Our MPS™ sensor technology has been designed for today’s multi-gas environments, resists contamination and prevents sensor poisoning. Give your teams peace of mind with a purpose-built device in any environment. The MPS technology in our portable gas monitors detects hydrogen and common hydrocarbons automatically in one sensor. Our reliable and dependable Gasman with industry leading sensor technology that your applications demand.

Gasman MPS™ provides a ‘TrueLEL™’reading for all flammable gases in any multi species environment without requiring calibration or scheduled maintenance over its 5-year+ lifecycle, reducing interruptions to your operations and increases up-time. Being poison resistant and withbattery life doubled, operators are more likely to never be without a device. Gasman MPS™ is ATEX Zone 0 approved enabling operators to enter an area in which an explosive gas atmosphere is present continuously or for long periods without fear their Gasman will ignite their environment. 

T4x

T4xAs the industry is continuously demanding improvements in safety, reduced environmental impact, and lower cost of ownership; our reliable and dependable portable T4x gas monitor meets those needs with its industry-leading sensor technologies. It is specifically designed to meet the demands of your applications. 

T4x helps operations teams focus on more value adding tasks by reducing the number of sensor replacementsby 75% and increasing sensor reliability.    

Through ensuring compliance across site T4x helps health and safety managers by eliminating the need to ensure each device is calibratedfor the relevant flammable gas as it accurately detects over 15 at once. Being poison resistant and withbattery life doubled, operators are more likely to never be without a device.​ T4x reduces the 5-year total cost of ownership by over 25% and saves 12g of lead per detector which makes it much easier to recycle at the end of its life, and better for the planet​. 

For more on Crowcon, visit https://www.crowcon.com or for more on MPS visit https://www.crowcon.com/mpsinfixed/

An Introduction to the Oil and Gas Industry 

The oil and gas industry is one of the biggest industries in the world, making a significant contribution to the global economy. This vast sector is often separated into three main sectors: upstream, midstream and downstream. Each sector comes with their own unique gas hazards. 

Upstream

The upstream sector of the oil and gas industry, sometimes referred to as exploration and production (or E&P), is concerned with locating sites for oil and gas extraction the subsequent drilling, recovery and production of crude oil and natural gas. Oil and gas production is an incredibly capital-intensive industry, requiring the use of expensive machinery equipment as well as highly skilled workers. The upstream sector is wide-ranging, encompassing both onshore and offshore drilling operations. 

The major gas hazard encountered in upstream oil and gas is hydrogen sulphide (H2S), a colourless gas known by its distinct rotten egg like smell. H2S is a highly toxic, flammable gas which can have harmful effects on our health, leading to loss of consciousness and even death at high levels. 

Crowcon’s solution for hydrogen sulphide detection comes in the form of the XgardIQ, an intelligent gas detector which increases safety by minimising the time operators must spend in hazardous areas. XgardIQ is available with high-temperature H2S sensor, specifically designed for the harsh environments of the Middle East. 

Midstream

The midstream sector of the oil and gas industry encompasses the storage, transportation and processing of crude oil and natural gas. The transportation of crude oil and natural gas is done by both land and sea with large volumes transported in tankers and marine vessels. On land, transportation methods used are tankers and pipelines. Challenges within the midstream sector include but are not limited to maintaining the integrity of storage and transportation vessels and protecting workers involved in cleaning, purging and filling activities. 

Monitoring of storage tanks is essential to ensure the safety of workers and machinery. 

Downstream

The downstream sector refers to the refining and processing of natural gas and crude oil and the distribution of finished products. This is the stage of the process where these raw materials are transformed into products which are used for a variety of purposes such as fuelling vehicles and heating homes.  

The refining process for crude oil is generally split into three basic steps: separation, conversion and treatment. Natural gas processing involves separating the various hydrocarbons and fluids to produce ‘pipeline quality’ gas. 

The gas hazards which are typical within the downstream sector are hydrogen sulphide, sulphur dioxide, hydrogen and a wide range of toxic gases. Crowcon’s Xgard and Xgard Bright fixed detectors both offer a wide range of sensor options to cover all the gas hazards present in this industry. Xgard Bright is also available with the next generation MPS™ sensor, for the detection of over 15 flammable gases in one detector. Also available are both single and multi-gas personal monitors to ensure workers safety in these potentially hazardous environments. These include the Gas-Pro and T4x, with Gas-Pro providing 5 gas support in a compact and rugged solution.

A brief history of gas detection 

The evolution of gas detection has changed considerably over the years. New, innovative ideas from canaries to portable monitoring equipment provides workers with continuous precise gas monitoring. 

The Industrial Revolution was the catalyst in the development in gas detection due to the use of fuel that showed great promise, such as coal. As coal can be extracted from the earth through either mining or underground mining, tools like helmets and flame lights were their only protection from the dangers of methane exposure underground that were yet to be discovered. Methane gas is colourless and odourless, making it hard to know it’s presence until a noticeable pattern of health problems was discovered. The risks of gas exposure resulted in experimenting with detection methods to preserve the safety of the workers for years to come. 

A Need for Gas Detection 

Once gas exposure became apparent, miners understood that they needed to know whether the mine had any pocket of methane gas where they were working. In the early 19th century, the first gas detector was recorded with many miners wearing flame lights on their helmets to be able to see while they were working, so being able to detect the extremely flammable methane was paramount. The worker would wear a thick, wet blanket over their bodies while carrying a long wick with the end lit on fire. Entering the mines, the individual would move the flame around and along the walls looking for gas pockets. If found, a reaction would ignite and be noted to the crew while the person detecting was protected from the blanket. With time, more advanced methods of detecting gas were developed. 

The Introduction of Canaries 

Gas detection moved from humans to canaries due to their loud chirps and similar nervous systems for controlling breathing patterns. The canaries were placed in certain areas of the mine, from there, workers would check on the canaries to care for them as well as see if their health had been affected. During the work shifts, miners would listen to the canaries chirp. If a canaries began to shake its cage, that was a strong indicator of a gas pocket exposure in which it has started to affect its health. Miners would then evacuate the mine and noted that it was unsafe to enter. On some occasions if the canary stopped chirping all together, miners knew to make a swifter exit before the gas exposure had a chance to affect their health. 

The Flame Light 

The flame light was the next evolution for gas detection in the mine, as a result of worries about animal safety. Whilst providing light for the miners, the flame was housed in a flame-arrestor shell which absorbed any heat and captured the flame to prevent it from igniting any methane that may be present. The outside shell contained a glass piece with three incisions running horizontally. The middle line was set as the ideal gas environment while the bottom line indicated an oxygen-deficient environment, and the top line indicated methane exposure or an oxygen-enriched environment. Miners would light the flame in an environment with fresh air. If the flame lowered or started to die, it would indicate that the atmosphere had a low oxygen concentration. If the flame grew larger, the miners knew that methane was present with oxygen, both cases indicating that they needed to leave the mine. 

The Catalytic Sensor 

Although the flame light was a development in gas detection technology, it however, was not a ‘one size fits all’ approach for all industries. Therefore, the catalytic sensor was the first gas detector that has a resemblance to modern technology. The sensors work on the principle that when a gas oxidises, it produces heat. The catalytic sensor works through temperature change, which is proportional to the concentration of gas. Whilst this was a step forward in the development of the technology required for gas detection, it still initially required manual operation in order to receive a reading. 

Modern Day Technology 

Gas detection technology has been developed tremendously since the early 19th century in which the first gas detector was recorded. With now over five different types of sensors commonly used across all industries, including Electrochemical, Catalytic Beads (Pellistor), Photoionisation detector (PID) and Infrared Technology (IR), along with the most modern sensors Molecular Property Spectrometer™ (MPS) and Long-Life Oxygen (LLO2), modern day gas detectors are highly sensitive, accurate but most importantly reliable, all of which allow for all personnel to stay safe reducing the number of workplace fatalities. 

The Benefits of MPS Sensors 

Developed by NevadaNano, Molecular Property Spectrometer™ (MPS™) sensors represent the new generation of flammable gas detectors. MPS™ can quickly detect over 15 characterised flammable gases at once. Until recently, anyone who needed to monitor flammable gases had to select either a traditional flammable gas detector containing a pellistor sensor calibrated for a specific gas, or containing an infra-red (IR) sensor which also varies in output according to the flammable gas being measured, and hence needs to be calibrated for each gas. While these remain beneficial solutions, they are not always ideal. For example, both sensor types require regular calibration and the catalytic pellistor sensors also need frequent bump testing to ensure they have not been damaged by contaminants (known as ‘sensor poisoning’ agents) or by harsh conditions. In some environments, sensors must frequently be changed, which is costly in terms of both money and downtime, or product availability. IR technology cannot detect hydrogen – which has no IR signature, and both IR and pellistor detectors sometimes incidentally detect other (i.e., non-calibrated) gases, giving inaccurate readings that may trigger false alarms or concern operators. 

The MPS™ sensor delivers key features that provide real world tangible benefits to operator and hence workers. These include: 

No calibration  

When implementing a system containing a fixed head detector, it is common practice to service on a recommended schedule defined by manufacturer. This entails ongoing regular costs as well potentially disrupting production or process in order service or even gain access to detector or multiple detectors. There may also be a risk to personnel when detectors are mounted in particularly hazardous environments. Interaction with an MPS sensor is less stringent because there are no unrevealed failure modes, provided air is present. It would be wrong to say there is no calibration requirement. One factory calibration, followed by a gas test when commissioning is sufficient, because there is an internal automated calibration being performed every 2 seconds throughout the working life of the sensor. What is really meant is – no customer calibration. 

The Xgard Bright with MPS™ sensor technology does not require calibration. This in turn reduces the interaction with the detector resulting in a lower total cost of ownership over the sensor life cycle and reduced risk to personnel and production output to complete regular maintenance. It is still advisable to check the cleanliness of the gas detector from time to time, since gas can’t get through thick build ups of obstructive material and wouldn’t then reach the sensor. 

Multi species gas – ‘True LEL’™  

Many industries and applications use or have as a by-product multiple gases within the same environment. This can be challenging for traditional sensor technology which can detect only a single gas that they were calibrated for at the correct level and can result in inaccurate reading and even false alarms which can halt process or production if another flammable gas type is present. The lack of response or over response frequently faced in multi gas environments can be frustrating and counterproductive compromising safety of best user practices. The MPS™ sensor can accurately detect multiple gases at once and instantly identify gas type. Additionally, the MPS™ sensor has a on board environmental compensation and does not require an externally applied correctional factor. Inaccurate readings and false alarms are a thing of the past.  

No sensor poisoning  

In certain environments traditional sensor types can be under risk of poisoning. Extreme pressure, temperature, and humidity all have the potential to damage sensors whist environmental toxins and contaminants can ‘poison’ sensors, leading to severely compromised performance. Detectors in environments where poisons or inhibitors may be encountered, regular and frequent testing is the only way to ensure that performance is not being degraded. Sensor failure due to poisoning can be a costly experience. The technology in the MPS™ sensor is not affected by contaminates in the environment. Processes that have contaminates now have access to a solution that operates reliably with fail safe design to alert operator to offer a peace of mind for personnel and assets located in hazardous environment. Additionally, the MPS sensor is not harmed by elevated flammable gas concentrations, which may cause cracking in conventional catalytic sensor types for example. The MPS sensor carries on working. 

Hydrogen (H2)

The usage of Hydrogen in industrial processes is increasing as the focus to find a cleaner alternative to natural gas usage. Detection of Hydrogen is currently restricted to pellistor, metal oxide semiconductor, electrochemical and less accurate thermal conductivity sensor technology due to Infra-Red sensors inability to detect Hydrogen. When faced with challenges highlighted above in poisoning or false alarms, the current solution can leave operator with frequent bump testing and servicing in addition to false alarm challenges. The MPS™ sensor provides a far better solution for Hydrogen detection, removing the challenges faced with traditional sensor technology. A long-life, relatively fast responding hydrogen sensor that does not require calibration throughout the life cycle of the sensor, without the risk of poisoning or false alarms, can significantly save on total cost of ownership and reduces interaction with unit resulting in peace of mind and reduced risk for operators leveraging MPS™ technology. All of this is possible thanks to MPS™ technology, which is the biggest breakthrough in gas detection for several decades. The Gasman with MPS is hydrogen (H2) ready. A single MPS sensor accurately detects hydrogen and common hydrocarbons in a fail-safe, poison-resistant solution without recalibration.

For more on Crowcon, visit https://www.crowcon.com or for more on MPSTM visit https://www.crowcon.com/mpsinfixed/  

World Hydrogen Summit 2022

Crowcon exhibited at the World Hydrogen Summit & Exhibition 2022 on the 9th – 11th May 2022 as part of the event designed to advance development in the hydrogen sector. Based in Rotterdam and produced by the Sustainable Energy Council (SEC), this year’s exhibition was the first Crowcon has attended. We were excited to be part of an occasion which fosters connections and collaboration between those at the forefront of the heavy industry and drives the hydrogen sector forward.

Our team representatives met various industry peers and showcased our Hydrogen solutions for gas detection. Our MPS sensor offers a higher standard of flammable gas detection thanks to its pioneering advanced molecular property spectrometer (MPS™) technology that can detect and accurately identify over 15 different flammable gases. This showcased an ideal solution for hydrogen detection due to hydrogen having proprieties that allow for easy ignition and higher burn intensity compared to that of petrol or diesel, therefore poses a real explosion risk. To find out more read our blog.

Our MPS technology had interest due to this not requiring calibration throughout the life cycle of the sensor, and detects flammable gases without the risk of poisoning or false alarms, thereby having a significant saving on total cost of ownership and reduce interaction with units, ultimately providing peace of mind and less risk for operators.

The Summit allowed us to understand the current state of the hydrogen market, including key players and current projects, allowing for potential developed a greater understanding of our product needs in order to play a major role in the future of hydrogen gas detection.

We look forward to attending next year!

T4x a Compliance 4-gas monitor 

It is vital to ensure that the gas sensor you employ is fully optimised and reliable in the detection and accurate measurement of flammable gas and vapours, whatever environment or workplace it is within, is of the utmost importance. 

Fixed or portable? 

Gas detectors come in a range of different forms, most commonly they are known as fixed, portable or transportable, in which these devices are designed to meet the needs of the user and environment whilst protecting the safety of those within it.  

Fixed detectors are implemented as permanent fixtures within an environment to provide ongoing monitoring of plant and equipment. According to guidance from the Health and Safety Executive (HSE) these types of sensors are particularly helpful where there is the possibility of a leak into an enclosed or partially enclosed space which could lead to the accumulation of flammable gases. The International Gas Carrier Code (IGC Code) states that gas detection equipment should be installed to monitor the integrity of the environment that it is to monitor and should be tested in accordance with the recognised standards. This is to ensure that the fixed gas detection system operates effectively, timely and accurate calibration of the sensors is critical. 

Portable detectors normally come as a small, handheld device that can be used within smaller environments, confined spaces, to trace leaks or early warnings to the presence of flammable gas and vapour within hazardous areas. Transportable detectors are not handheld, but they are easily moved from place to place to act as a monitor ‘stand-in’ whilst a fixed sensor is undergoing maintenance. 

What is a compliance 4-gas monitor? 

Gas sensors are primarily optimised for detecting specific gases or vapours through design or calibration. It is desirable that a toxic gas sensor, for example one detecting carbon monoxide or hydrogen sulphide, provides an accurate indication of the target gas concentration rather than a response to another interfering compound. Personal safety monitors often combine several sensors for protecting the user against specific gas risks. However, a ‘Compliance 4-Gas monitor’ comprises sensors for measuring levels of carbon monoxide (CO) hydrogen sulphide (H2S), oxygen (O2) and flammable gases; normally methane (CH4) in one device.  

The T4x monitor with the ground-breaking MPS™ sensor is able to provide protection from CO, H2S, O2 risks with accurate measurement of multiple flammable gases and vapours utilising a basic methane calibration. 

Is there a need for a compliance 4-gas monitor? 

Many of the flammable gas sensors deployed in conventional monitors are optimized for detecting a specific gas or vapour through calibration but will respond to many other compounds. This is problematic and potentially dangerous as the gas concentration indicated by the sensor will not be accurate and may indicate a higher (or more dangerously) and lower concentration of gas/vapour than is present. With workers often potentially exposed to risks from multiple flammable gases and vapours within their workplace, it is incredibly important to ensure that they are protected through the implementation of an accurate and reliable sensor. 

How is the T4x portable 4-in-1 gas detector different? 

To ensure ongoing reliability and accuracy of the T4x detector. The detector utilises the  MPS™ (Molecular Property Spectrometry) Sensor functionality within its robust unit that provides a range of features to ensure safety. It offers protection against the four common gas hazards: carbon monoxide, hydrogen sulphide, flammable gases and oxygen depletion, whilst The T4x multi gas detector now comes with improved detection of pentane, hexane and other long chain hydrocarbons. It comprises a large single button and easy-to-follow menu system to enable ease of use for those wearing gloves, who’ve undergone minimal training. Tough, yet portable, the T4x detector features an integrated rubber boot and an optional clip-on filter that can be easily removed and replaced when needed. These features allow the sensors to remain protected even within the dirtiest environments, to ensure they can constant. 

A unique benefit to the T4x detector is that it ensures toxic gas exposure is calculated accurately throughout an entire shift, even if it is switched off momentarily, during a break or when travelling to another site. The TWA feature allows for uninterrupted and disrupted monitoring, So, when powering up, the detector begins again from zero, as if starting a new shift and ignores all previous measurements. The T4x allows the user the option to include previous measurements from within the correct time frame. The detector is not just reliable in terms of accurate detection and measurement of four gases, it is also dependable due to its battery life. It lasts for 18 hours and is useful for usage across multiple or longer shifts without requiring charging as regularly.  

During usage the T4 employs a handy ‘traffic light’ display offering constant visual assurance that it is operating soundly and conforming to the site bump test and calibration policy. The bright green and red Positive Safety LEDs are visible to all and, as a result, offer a quick, simple and comprehensive indication of the monitor’s status to both the user and others around them. 

T4x helps operations teams focus on more value adding tasks by reducing the number of sensor replacements by 75% and increasing sensor reliability. Through ensuring compliance across site T4x helps health and safety managers by eliminating the need to ensure each device is calibrated for the relevant flammable gas as it accurately detects 19 at once. Being poison resistant and with battery life doubled, operators are more likely to never be without a device. T4x reduces the 5-year total cost of ownership by over 25% and saves 12g of lead per detector which makes it much easier to recycle at the end of its life. 

Overall, through the combination of three sensors (including two new sensor technologies MPS and Long-life O2) within an already popular portable multi-gas detector. Crowcon allowed for the enhancement of safety, cost-effectiveness and efficiency of individual units and entire fleets. The new T4x offers longer life with a higher accuracy for gas hazard detection whilst providing a more sustainable build than ever before. 

How Long will my Gas Sensor Last?

Gas detectors are used extensively within many industries (such as water treatment, refinery, petrochemical, steel and construction to name a few) to protect personnel and equipment from dangerous gases and their effects. Users of portable and fixed devices will be familiar with the potentially significant costs of keeping their instruments operating safely over their operational life. Gas sensors are understood to provide a measurement of the concentration of some analyte of interest, such as CO (carbon monoxide), CO2 (carbon dioxide), or NOx (nitrogen oxide). There are two most used gas sensors within industrial applications: electrochemical for toxic gases and oxygen measurement, and pellistors (or catalytic beads) for flammable gases. In recent years, the introduction of both Oxygen and MPS (Molecular Property Spectrometer) sensors have allowed for improved safety.  

How do I know when my sensor has failed? 

There have been several patents and techniques applied to gas detectors over the past few decades which claim to be able to determine when an electrochemical sensor has failed. Most of these however, only infer that the sensor is operating through some form of electrode stimulation and might provide a false sense of security. The only sure method of demonstrating that a sensor is working is to apply test gas and measure the response: a bump test or full calibration. 

Electrochemical Sensor  

Electrochemical sensors are the most used in diffusion mode in which gas in the ambient environment enters through a hole in the face of the cell. Some instruments use a pump to supply air or gas samples to the sensor. A PTFE membrane is fitted over the hole to prevent water or oils from entering the cell. Sensor ranges and sensitivities can be varied in design by using different size holes. Larger holes provide higher sensitivity and resolution, whereas smaller holes reduce sensitivity and resolution but increase the range. 

Factors affecting Electrochemical Sensor Life 

There are three main factors that affect the sensor life including temperature, exposure to extremely high gas concentrations and humidity. Other factors include sensor electrodes and extreme vibration and mechanical shocks.  

Temperature extremes can affect sensor life. The manufacturer will state an operating temperature range for the instrument: typically -30˚C to +50˚C. High quality sensors will, however, be able to withstand temporary excursions beyond these limits. Short (1-2 hours) exposure to 60-65˚C for H2S or CO sensors (for example) is acceptable, but repeated incidents will result in evaporation of the electrolyte and shifts in the baseline (zero) reading and slower response. 

Exposure to extremely high gas concentrations can also compromise sensor performance. Electrochemical sensors are typically tested by exposure to as much as ten-times their design limit. Sensors constructed using high quality catalyst material should be able to withstand such exposures without changes to chemistry or long-term performance loss. Sensors with lower catalyst loading may suffer damage.  

The most considerable influence on sensor life is humidity. The ideal environmental condition for electrochemical sensors is 20˚Celsius and 60% RH (relative humidity). When the ambient humidity increases beyond 60%RH water will be absorbed into the electrolyte causing dilution. In extreme cases the liquid content can increase by 2-3 times, potentially resulting in leakage from the sensor body, and then through the pins. Below 60%RH water in the electrolyte will begin to de-hydrate. The response time may be significantly extended as the electrolyte or dehydrated. Sensor electrodes can in unusual conditions be poisoned by interfering gases that adsorb onto the catalyst or react with it creating by-products which inhibit the catalyst.  

Extreme vibration and mechanical shocks can also harm sensors by fracturing the welds that bond the platinum electrodes, connecting strips (or wires in some sensors) and pins together.  

‘Normal’ Life Expectancy of Electrochemical Sensor 

Electrochemical sensors for common gases such as carbon monoxide or hydrogen sulphide have an operational life typically stated at 2-3 years. More exotic gas sensor such as hydrogen fluoride may have a life of only 12-18 months. In ideal conditions (stable temperature and humidity in the region of 20˚C and 60%RH) with no incidence of contaminants, electrochemical sensors have been known to operate more than 4000 days (11 years). Periodic exposure to the target gas does not limit the life of these tiny fuel cells: high quality sensors have a large amount of catalyst material and robust conductors which do not become depleted by the reaction. 

Pellistor Sensor 

Pellistor sensors consist of two matched wire coils, each embedded in a ceramic bead. Current is passed through the coils, heating the beads to approximately 500˚C. Flammable gas burns on the bead and the additional heat generated produces an increase in coil resistance which is measured by the instrument to indicate gas concentration. 

Factors affecting Pellistor Sensor Life 

The two main factors that affect the sensor life include exposure to high gas concentration and poising or inhibition of the sensor. Extreme mechanical shock or vibration can also affect the sensor life. The capacity of the catalyst surface to oxidise the gas reduces when it has been poisoned or inhibited. Sensor life more than ten years is common in applications where inhibiting or poisoning compounds are not present. Higher power pellistors have greater catalytic activity and are less vulnerable to poisoning. More porous beads also have greater catalytic activity as their surface volume in increased. Skilled initial design and sophisticated manufacturing processes ensure maximum bead porosity. Exposure to high gas concentrations (>100%LEL) may also compromise sensor performance and create an offset in the zero/base-line signal. Incomplete combustion results in carbon deposits on the bead: the carbon ‘grows’ in the pores and creates mechanical damage. The carbon may however be burned off over time to re-reveal catalytic sites. Extreme mechanical shock or vibration can in rare cases also cause a break in the pellistor coils. This issue is more prevalent on portable rather than fixed-point gas detectors as they are more likely to be dropped, and the pellistors used are lower power (to maximise battery life) and thus use more delicate thinner wire coils. 

How do I know when my sensor has failed? 

A pellistor that has been poisoned remains electrically operational but may fail to respond to gas. Hence the gas detector and control system may appear to be in a healthy state, but a flammable gas leak may not be detected. 

Oxygen Sensor 

Long Life 02 Icon

Our new lead-free, long-lasting oxygen sensor does not have compressed strands of lead the electrolyte has to penetrate, allowing a thick electrolyte to be used which means no leaks, no leak induced corrosion, and improved safety. The additional robustness of this sensor allows us to confidently offer a 5-year warranty for added piece of mind. 

Long life-oxygen sensors have an extensive lifespan of 5-years, with less downtime, lower cost of ownership, and reduced environmental impact. They accurately measure oxygen over a broad range of concentrations from 0 to 30% volume and are the next generation of O2 gas detection. 

MPS Sensor  

MPS sensor provides advanced technology that removes the need to calibrate and provides a ‘True LEL (lower explosive limit)’ for reading for fifteen flammable gases but can detect all flammable gases in a multi-species environment, resulting in lower ongoing maintenance costs and reduced interaction with the unit. This reduces risk to personnel and avoids costly downtime. The MPS sensor is also immune to sensor poisoning.  

Sensor failure due to poisoning can be a frustrating and costly experience. The technology in the MPS™ sensor is not affected by contaminates in the environment. Processes that have contaminates now have access to a solution that operates reliably with fail safe design to alert operator to offer a peace of mind for personnel and assets located in hazardous environment. It is now possible to detect multiple flammable gases, even in harsh environments, using just one sensor that does not require calibration and has an expected lifespan of at least 5 years. 

The Dangers of Hydrogen

As a fuel, hydrogen is highly flammable and leaks generate a serious risk of fire. However, hydrogen fires are markedly different to fires involving other fuels. When heavier fuels and hydrocarbons, like petrol or diesel, leak they pool close to the ground. In contrast, hydrogen is one of the lightest elements on earth, so when a leak occurs the gas rapidly disperses upwards. This makes ignition less likely, but a further difference is that hydrogen ignites and burns more easily than petrol or diesel. In fact, even a spark of static electricity from a person’s finger is enough to set off an explosion when hydrogen is available. Hydrogen flame is also invisible, so it is hard to pin-point where is the actual ‘fire’ is, but it generates a low radiant heat due to the absence of carbon and tends to burn out quickly.

Hydrogen is odourless, colourless and tasteless, so leaks are hard to detect using human senses alone. Hydrogen is non-toxic, but in indoor environments like battery storage rooms, it may build up and cause asphyxiation by displacing oxygen. This danger can be offset to some extent by adding odorants to hydrogen fuel, giving it an artificial smell and alerting users in case of a leak. But as hydrogen disperses quickly, the odorant is unlikely to travel with it. Hydrogen leaking indoors quickly collects, initially at ceiling level and eventually fills up the room. Therefore, the placement of gas detectors is key in early detection of a leak.

Hydrogen is usually stored and transported in liquified hydrogen tanks. The last concern is that because it is compressed, liquid hydrogen is extremely cold. If hydrogen should escape from its tank and come in contact with skin it can cause severe frostbite, or even the loss of extremities.

Which sensor technology is best for detecting hydrogen?

Crowcon has a wide range of products for the detection of hydrogen. The traditional sensor technologies for flammable gas detection are pellistors and infrared (IR). Pellistor gas sensors (also called catalytic bead gas sensors) have been the primary technology for detecting flammable gases since the 1960s and you can read more about pellistor sensors on our solution page. However, their key disadvantage is that in low oxygen environments, pellistor sensors will not function properly and may even fail. In some installations, pellistors are at risk of being poisoned or inhibited, which leaves workers unprotected. Also, pellistor sensors are not fail-safe, and a sensor failure will not be detected unless test gas is applied.

Infrared-type sensors are a reliable way to detect flammable hydrocarbons in low oxygen environments. They are not susceptible to being poisoned, so IR can significantly enhance safety in these conditions. Read more about IR sensors on our solution page, and the differences between pellistors and IR sensors in the following blog.

Just as pellistors are susceptible to poisoning, IR sensors are susceptible to severe mechanical and thermal shock and are also strongly affected by gross pressure changes. Additionally, IR sensors cannot be used to detect hydrogen. So the best option for hydrogen flammable gas detection is molecular property spectrometer (MPS™) sensor technology. This does not require calibration throughout the life cycle of the sensor, and since MPS detects flammable gases without the risk of poisoning or false alarms, it can significantly save on total cost of ownership and reduce interaction with units, resulting in peace of mind and less risk for operators. Molecular property spectrometer gas detection was developed at the University of Nevada and is currently the only gas detection technology able to detect multiple flammable gases, including hydrogen, simultaneously, very accurately and with a single sensor.

Read our white paper to find out more about our MPS sensor technology, and for more info on hydrogen gas detection visit our  industry page and have a look at some of our other hydrogen resources:

What do you need to know about Hydrogen?

Green Hydrogen – An Overview

Blue Hydrogen – An Overview

Xgard Bright MPS provides hydrogen detection in energy storage application