Gas Hazards in Battery Power Storage

Batteries are effective at reducing power outages since they can also store excess traditional grid energy. The energy stored within batteries can be released whenever a large volume of power is needed, such as during a power failure at a data centre to prevent data being lost, or as a back-up power supply to a hospital or military application to ensure the continuity of vital services. Large scale batteries can also be used to plug short-term gaps in demand from the grid. These battery compositions can also be used in smaller sizes to power electric cars and may be further scaled down to power commercial products, such as phones, tablets, laptops, speakers and – of course – personal gas detectors.

Gas hazards

The main gas risk emitted by batteries, specifically lead acid batteries, is hydrogen. It is possible to get both hydrogen and oxygen evolved during charging however, a lead acid battery is likely to have catalytic recombination parts internally, so oxygen is less of a risk. Hydrogen is always a cause for concern, as it can collect and build up. A situation that is obviously worsened when they are charged in a space with a poor airflow.

When charging, lead-acid batteries consist of lead and oxide at the positive terminal, and of spongy lead at the negative anode, using concentrated sulfuric acid as the electrolyte. The presence of sulfuric acid is another cause for concern if the battery leaks or is ever damaged because concentrated acids harm people, metals and the environment.

When charging batteries also emit oxygen and hydrogen because of the electrolysis process. The levels of hydrogen produced soar when a lead acid battery cell “blows” or is unable to be charged properly. The amount of gas present is relevant because high levels of hydrogen make it highly explosive, even though it is not toxic. Hydrogen has a 100% lower explosive limit of 4.0% by volume, at which level an ignition source would cause fires or for hydrogen more usually, explosions. Fires and explosions are an issue not only for the workers within the space, but also for the surrounding equipment and infrastructure.

Importance of Gas Detection Technology

Gas detection is an invaluable safety technology often equipped in battery charging rooms. Ventilation is also advised, and while helpful, it is not fool proof as fan motors can fail and should not be relied upon as the sole safety measure for battery charging areas. Fans mask the problem while gas detection notifies personnel to act before problems escalate. Gas detection systems are crucial in informing personnel of increasing gas leaks before becoming dangerous. Gas detection units comply with local building codes and NFPA 111, the National Fire Protection Association standard on stored electrical energy emergency and standby power systems. They include maintenance, operation, installation, and testing provisions regarding the system’s performance. In addition to permanent gas detection systems, handheld units are available. The benchmark products are provided by Crowcon and are listed below.

Portable Gas Detectors

Crowcon’s portable gas detectors (Gasman, Gas-Pro, T4x, Tetra 3 and T4) protect against a wide range of industrial gas hazards, with both single gas and multi-gas monitors available. With a wide range of sizes and complexities, you can find the right portable gas detection solution to meet the number and type of gas sensors you need and your display and certification requirements.

Fixed Gas Detectors

Crowcon gas detection fixed systems offer a flexible range of solutions that can measure flammable, toxic, and oxygen gases, report their presence, and activate alarms or associated equipment. Crowcon fixed gas monitoring systems (Xgard, Xgard Bright and XgardIQ) are designed to be interfaced with manual call points, fire and gas detectors, and distributed control systems (DCS).

Control Panels

Crowcon gas detection control panels offer a flexible range of solutions that can measure flammable, toxic, and oxygen gases, report their presence, and activate alarms or associated equipment. Crowcon fixed gas (Vortex, GM Addressable Controllers, Gasmaster) monitoring systems are designed to be interfaced with manual call points, fire and gas detectors and distributed control systems (DCS). In addition, each system can be engineered to drive remote annunciators and mimic panels. Crowcon has a gas detection product to suit your application regardless of your operation.

Temperature Measurement

Crowcon has extensive experience with temperature measurement. There are several models of temperature measurement, from pocket thermometers to industrial kits ranging from -99.9 to 299.9°C with probes and clamps. They are enhancing their fixed detection capabilities by adding high-temperature electrochemical sulphur dioxide detection for battery manufacturing and charging stations. This is critical during the first charge of a battery, as a fault is most likely at that time. Their fast-acting systems detect the precursors to thermal runaway and quickly terminate power to the batteries to avoid damage.

To find out more on the dangers of gas hazards in battery power visit our industry page for more information.

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Xgard Type 3: The mV Advantage

Xgard Type 3 is the ideal solution for detecting lighter-than-air flammable gases such as methane and hydrogen. Detectors in such applications usually have to be mounted high-up in roof spaces or above equipment where access for calibration and maintenance is likely to present problems.

Gas detectors require calibration (usually every six months) and sensors may need to be replaced every 3-5 years. These activities usually require direct access to the detector to make adjustments and replace parts. National regulations such as the ‘UK Work at Height Regulations 2005’ stipulate safe working practices when working on equipment at height, and compliance usually requires the use of scaffolding or mobile ‘cherry pickers’ which entails significant cost and disruption on-site.

The advantage of mV pellistor type detectors

The terms ‘mV’ and ‘4-20mA’ describe the type of signal which is transmitted through the cable between the gas detector and the control system (for example a Crowcon Gasmaster). Calibration of 4-20mA detector (e.g. Xgard Type 5) entails removing the lid, and zeroing/calibrating the amplifier using a meter, test-points and potentiometers. Even more sophisticated detectors with a display and non-intrusive calibration still require direct access to operate the menu system using a magnet in order to perform calibration.

Xgard Type 3 is a mV pellistor-based detector which has no internal electronics (i.e. no amplifier); just terminals to connect via three wires to the control system (e.g. Gasmaster). Commissioning simply entails measuring the ‘head voltage’ at the detector terminals, and performing zero and calibration adjustments at the Gasmaster input module. Ongoing 6-monthly calibrations are then performed by remotely applying gas (via a ‘spray deflector’ or ‘collector cone’ accessory), and any necessary adjustments are made at ground level via the control system input module.

Hence once commissioned, mV pellistor type detectors do not need to be accessed until the sensor needs replacing; usually 3-5 years after installation. The routine need for expensive access equipment; scaffolding or cherry-pickers in thus avoided.

Xgard Type 3 can be directly connected to Gasmaster and Gasmonitor systems, and to Vortex via an ‘Accessory Enclosure’ accessory which converts the mV signals to 4-20mA.

Remote calibration of a mV pellistor type detector.

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The Importance of Gas Detection in the Power Industry

The energy industry is the very backbone of our industrial and domestic worlds, supplying essential energy to industrial, manufacturing, commercial and residential customers around the globe. With the inclusion of fossil fuel industries (petroleum, coal, LNG); electricity generation, distribution and sales; nuclear energy and renewable energy, the power generation sector is essential in supporting the increasing demand for power from emerging countries and an increasing world population.

Gas Hazards in Power Sector

Gas detection systems have been installed extensively in the power industry to minimise potential consequence through the detection of gas exposure with those working within this industry are exposed to a variation of power plant gas hazards.

Carbon monoxide

The transport and pulverisation of coal poses a high risk of combustion. Fine coal dust becomes suspended in air and highly explosive. The smallest spark, for example from plant equipment, can ignite the dust cloud and cause an explosion that sweeps up more dust, which explodes in turn, and so on in a chain reaction. Coal power plants now require combustible dust certification, in addition to hazardous gas certification.

Coal power plants generate large volumes of carbon monoxide (CO) which is both highly toxic and flammable and must be accurately monitored. A toxic component of incomplete combustion, CO comes from boiler casing leaks and smouldering coal. It is vital to monitor CO in coal tunnels, bunkers, hoppers and tipper rooms, along with infrared-type flammable gas detection to detect pre-fire conditions.

Hydrogen

With hydrogen fuel cells gaining popularity as alternatives to fossil fuel, it is important to be aware of the dangers of hydrogen. Like all fuels, hydrogen is highly flammable and if it leaks there is real risk of fire. Hydrogen burns with a pale blue, almost invisible, flame that can cause serious injuries and severe equipment damage. Therefore, hydrogen must be monitored, to prevent seal-oil system fires, unscheduled shutdowns and to protect personnel from fire.

In addition, power plants must have back-up batteries, to ensure the continued functioning of critical control systems in cases of power outage. Battery rooms generate considerable hydrogen, and monitoring is often carried out in conjunction with ventilation. Traditional lead acid batteries produce hydrogen when they are being charged. These batteries are normally charged together, sometimes in the same room or area, which can generate an explosion risk, especially if the room is not properly ventilated.

Confined Space Entry

Confined space entry (CSE) is often considered to be a dangerous type of work performed in power generation. It is therefore important that the entry is strictly controlled and detailed precautions are taken. Lack of oxygen, toxic and flammable gases are risks that can occur during work in confined spaces, which should never be considered as simple or routine. However, the hazards of working in confined spaces can be predicted, monitored, and mitigated through the use of portable gas detection devices. Confined Spaces Regulations 1997. Approved Code of Practice, Regulations and guidance is for employees that work in Confined Spaces, those who employ or train such people and those who represent them.

Our Solutions

Elimination of these gas hazards is virtually impossible, so permanent workers and contractors must depend on reliable gas detection equipment to protect them. Gas detection can be provided in both fixed and portable forms. Our portable gas detectors protect against a wide range of gas hazards, these include T4x, Gasman, Tetra 3, Gas-Pro, T4, and Detective+. Our fixed gas detectors are used in many applications where reliability, dependability and lack of false alarms are instrumental to efficient and effective gas detection, these include Xgard, Xgard Bright, XgardIQ and IRmax. Combined with a variety of our fixed detectors, our gas detection control panels offer a flexible range of solutions that measure flammable, toxic and oxygen gases, report their presence and activate alarms or associated equipment, for the power industry our panels include Vortex and Gasmonitor.

To find out more on the gas hazards in the power industry visit our industry page for more information.

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The importance of gas detection in the Petrochemical Industry

Closely linked to oil and gas, the petrochemicals industry takes raw materials from refining and gas processing and, through chemical process technologies, converts them into valuable products. In this sector, the organic chemicals produced in the largest volumes are methanol, ethylene, propylene, butadiene, benzene, toluene and xylenes (BTX). These chemicals are the building blocks of many consumer goods including plastics, clothing fabric, construction materials, synthetic detergents and agrichemical products.

Potential Hazards

Exposure to potential hazardous substances is more likely to occur during shutdown or maintenance work as these are a deviation from the refinery’s routine operations. As these deviations are out of normal routine, care should be exercised at all times to avoid the inhalation of solvent vapours, toxic gases, and other respiratory contaminants. The assistance of constant automated monitoring is helpful in determining the presence of solvents or gases, allowing their associated risks to be mitigated. This includes warning systems such as gas and flame detectors, supported by emergency procedures, and permit systems for any kind of potentially dangerous work.

The petroleum industry is split into upstream, midstream and downstream and these are defined by the nature of the work that takes place in each area. Upstream work is typically known as the exploration and production (E&P) sector. Midstream refers to the transportation of products through pipelines, transit and oil tankers as well as the wholesale marketing of petroleum-based products. The downstream sector refers to the refining of petroleum crude oil, the processing of raw natural gas and the marketing and distribution of finished products.

Upstream

Fixed and portable gas detectors are needed to protect plant and personnel from the risks of flammable gas releases (commonly methane) as well as from high levels of H₂S, particularly from sour wells. Gas detectors for O₂ depletion, SO₂ and volatile organic compounds (VOCs) are required items of personal protection equipment (PPE), which is usually highly visible colour and worn near breathing space. Sometimes HF solution is used as a scouring agent. Key requirements for gas detectors are rugged and reliable design and long battery life. Models with design elements that support easy fleet management and compliance obviously have an advantage. You can read about VOC risk and Crowcon’s solution in our case study.

Midstream

Fixed monitoring of flammable gases situated close to pressure relief devices, filling and emptying areas is necessary to deliver early warning of localised leaks. Multi-gas portable monitors must be used to maintain personal safety, especially during work in confined spaces and supporting hot work permit area testing. Infrared technology in flammable gas detection supports purging with the ability to operate in inert atmospheres and delivers reliable detection in areas where pellistor type detectors would fail, due to poisoning or volume level exposure. You can read more on how infrared detection works in our blog and read our case study of infrared monitoring in refinery settings in Southeast Asia.

Portable laser methane detection (LMm) allows users to pin-point leaks at distance and in hard-to-reach areas, reducing the need for personnel to enter potentially dangerous environments or situations while performing routine or investigative leak monitoring. Using LMm is a quick and effective way to check areas for methane with a reflector, from up to 100m away. These areas include closed buildings, confined spaces and other difficult-to-reach areas such as above-ground pipelines that are near water or behind fences.

Downstream

In downstream refining, the gas risks may be almost any hydrocarbon, and may also include hydrogen sulphide, sulphur dioxide and other by-products. Catalytic flammable gas detectors are one of the oldest flammable gas detector types. They work well, but must have a bump testing station, to ensure each detector responds to the target gas and is still functional. The ongoing demand to reduce facility down-time whilst ensuring safety, especially during shutdown and turnaround operations, means that gas detection manufacturers must deliver solutions offering ease of use, straightforward training and reduced maintenance times, along with local service and support.

During plant shutdowns, processes are stopped, items of equipment are opened and checked and the number of people and moving vehicles at the site is many times higher than normal. Many of the processes undertaken will be hazardous and require specific gas monitoring. For example, welding and tank cleaning activities require area monitors as well as personal monitors to protect those on site.

Confined space

Hydrogen sulphide (H₂S) is a potential problem in the transport and storage of crude oil. The cleaning of storage tanks presents a high hazard potential. Many confined-space entry problems can occur here, including oxygen deficiency resulting from previous inerting procedures, rusting, and oxidation of organic coatings. Inerting is the process of reducing the oxygen levels in a cargo tank to remove the oxygen element required for ignition. Carbon monoxide can be present in the inerting gas. In addition to H₂S, depending on the characteristics of the product previously stored in the tanks, other chemicals that may be encountered include metal carbonyls, arsenic, and tetraethyl lead.

Our Solutions

Elimination of these gas hazards is virtually impossible, so permanent workers and contractors must depend on reliable gas detection equipment to protect them. Gas detection can be provided in both fixed and portable forms. Our portable gas detectors protect against a wide range of gas hazards, these include Clip SGD, Gasman, Tetra 3, Gas-Pro, T4, Gas-Pro TK and Detective+. Our fixed gas detectors are used in many applications where reliability, dependability and lack of false alarms are instrumental to efficient and effective gas detection, these include Xgard, Xgard Bright, Fgard IR3 Flame Detector and IRmax. Combined with a variety of our fixed detectors, our gas detection control panels offer a flexible range of solutions that measure flammable, toxic and oxygen gases, report their presence and activate alarms or associated equipment, for the petrochemical industry our panels include Addressable Controllers, Vortex and Gasmonitor.

To find out more on the gas hazards in the petrochemical industry visit our industry page for more information.

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Transportation and Key Gas Challenges

The transportation sector is one of the largest industries in the world, spanning a variety of applications. The sector offers services concerned with the movement of people and cargo of all types, across air freight and logistics, airlines and airport services, road and rail, transportation infrastructure, trucking, highways, rail tracks, and marine ports and services.

Gas hazards during transportation

The transport of dangerous goods is regulated in order to prevent, accidents involving people or property, damage to the environment. There a numerous gas hazards including the transportation of hazardous material, air conditioning emissions, cabin combustion and hangar leaks.

The transportation of hazardous materials poses a risk to those involved. There are nine classification areas specified by the United Nations (UN) including explosives, gases, flammable liquids and solids, oxidising substances, toxic substances, radioactive materials, corrosive substances and miscellaneous goods. With the risk of an accident occurring being more likely when transporting these materials. Although the biggest cause for concern within the industry being the transportation of non-flammable non-toxic gas is asphyxiation. As a slow leak in a storage container can drain all of the oxygen in the air and cause the individuals in the environment to suffocate.

Leaks within aircraft hangars and fuel storage areas of highly explosive aviation fuel is an area that must be monitored to prevent fires, equipment damage, and at the worst fatalities. It is essential to choose a suitable gas detection solution that focuses on the aircraft rather than the aircraft hangar, avoids false alarms, and can monitor large areas.

Not only is it the external environment that faces gas risks in transportation, those working in the sector also face similar challenges. Air conditioning emissions poses a gas hazard threat due to the burning of fossil fuels leading to a subsequent emission of carbon monoxide (CO). high levels of CO in a confined area such as a vehicle cabin, of more than the normal level (30ppm) or an oxygen level below normal (19%) can result in dizziness, feeling and being sick, tiredness and confusion, stomach pain, shortness of breath and difficulty breathing. Therefore, proper ventilation in these spaces with the assistance of a gas detector is paramount to ensuring the safe of those working in the transportation industry.

Similarly, in the air sector cabin combustion and fuselage fires, in the central portion of an airplane, poses a real threat. Although flame retardant materials are applied, if a fire does start the cabin’s trim and fittings can still generate toxic gases and vapours that could be more dangerous than the fire itself. Inhalation of harmful gases caused by a fire in these environments tend to be the main direct cause of fatalities.

Transportation Standards and Certifications

Each mode of transport, (road, rail, air, sea and inland waterway) has its own regulations but they are generally harmonized with the United Nations Economic Commission for Europe (UNECE). The Hazardous Materials Transportation Act (HMTA), enacted in the USA in 1975, states that regardless of the type of transportation, any company whose goods fall into one of the nine categories specified as hazardous by the UN, must comply with the regulations or risk fines and penalties.

Those working in the transport sector in the UK must comply with the requirements laid out in the UN Model Regulations which assigns each dangerous substance or article a specific class that correlates how dangerous it is. It does this via the packing group (PG) classification, according to PG I, PG II or PG III.

From an European standpoint the International Carriage of Dangerous Goods by Road (ADR) governs the regulations on how to classify, pack, label and certify dangerous goods. It also comprises vehicle and tank requirements and other operational requirements. The Carriage of Dangerous Goods and Use of Transportable Pressure Equipment Regulations (2009) also is relevant in England, Wales and Scotland.

Other relevant regulations include the International Carriage of Dangerous Goods by Inland Navigation (ADN), the International Maritime Dangerous Goods (IMDG) and The International Civil Aviation Organization’s (ICAO) Technical Instruction.

Our solution

Gas detection can be provided in both fixed and portable forms. Our portable gas detectors protect against a wide range of gas hazards, these include T4x, Clip SGD, Gasman, Tetra 3, Gas-pro, and T4. Our fixed gas detectors are used where reliability, dependability and lack of false alarms are instrumental to efficient and effective gas detection, these include Xgard, Xgard Bright, and IRmax. Combined with a variety of our fixed detectors, our gas detection control panels offer a flexible range of solutions which are able to measure flammable, toxic and oxygen gases, report their presence and activate alarms or associated equipment, for the transportation industry our panels include Gasmaster and Vortex.

To find out more on the dangers of gas hazards in transportation visit our industry page for more information.

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