Water Treatment: The Need For Gas Detection In Detecting Chlorine

Water utility companies help provide clean water for drinking, bathing, and industrial and commercial uses. Wastewater treatment plants and sewage systems help keep our waterways clean and sanitary. Throughout the water industry, the risk of gas exposure and gas-associated hazards are considerable. Harmful gases can be found in water tanks, service reservoirs, pumping wells, treatment units, chemical storage and handling areas, sumps, sewers, overflows, boreholes, and manholes.

What Is Chlorine and Why Is It Dangerous

Chlorine (Cl2) gas appears yellow green in colour, used to sterilise drinking water. However, most chlorine is used in the chemical industry with typical applications including water treatment as well as within the plastics and cleaning agents. Chlorine gas can be recognised by its pungent, irritating odour, which is like the odour of bleach. The strong smell may provide adequate warning to people that they are exposed. Cl2 itself is not flammable, but it can react explosively or form flammable compounds with other chemicals such as turpentine and ammonia.

Chlorine gas can be recognised by its pungent, irritating odour, which is like the odour of bleach. The strong smell may provide adequate warning to people that they are exposed. Chlorine is toxic and if inhaled or drunk in concentrated quantities can prove fatal. If chlorine gas is released into the air, people may be exposed through their skin, eyes or through inhalation. Chlorine is not combustible however can react with most combustibles which poses a fire and explosion risk. It also reacts violently with organic compounds such as ammonia and hydrogen, causing potential fire and explosion.

What is Chlorine used for

Water chlorination began in Sweden during the 18th century with the purpose to remove odours from water. This method continued to be used solely to remove odours from water until 1890 when chlorine was identified as an effective substance for disinfection purposes. Chlorine was first used for disinfection purposes in Great Britain in the early 1900’s which over the next century chlorination became the more favoured method used for water treatment and is now used for water treatment in most countries worldwide.

Chlorination is a method that can disinfect water with high levels of microorganisms where either chlorine or substance that contain chlorine is used to oxidise and disinfect the water. Different processes can be used to achieve safe levels of chlorine in drinking water to prevent against waterborne diseases.

Why Do I Need To Detect Chlorine

Chlorine, being denser than air, tends to disperse throughout low-lying zones in poorly ventilated or stagnant areas. Although non-flammable by itself, chlorine can become explosive when in contact with substances like ammonia, hydrogen, natural gas, and turpentine.

The reaction of the human body to chlorine depends on several factors; the concentration of chlorine present in air, the duration and frequency of exposure. Effects are also dependant on the health of an individual and the environmental conditions during exposure. For example, when small amounts of chlorine are breathed in during short time periods, this can affect the respirational system. Other effects vary from coughing and chest pains, to fluid accumulation in the lungs, skin and eye irritations. To note, these effects do not take place under natural conditions.

Our solution

The use of a chlorine gas detector provides detection and measurement of this substance in the air to prevent any accidents. Equipped with an electrochemical chlorine sensor, a fixed, or portable, single gas or multi gas Cl2 detector will monitor chlorine concentration in the ambient air. We have a wide range of gas detection products to help you meet the demands of the water treatment industry.

Fixed gas detectors are ideal to monitor and alert water treatment plant managers and workers to the presence of all the major gas hazards. The fixed gas detectors can be permanently positioned inside water tanks, sewage systems, and any other areas that present a high risk of gas exposure.

Portable gas detectors are lightweight and robust wearable gas detection devices. The portable gas detectors sound and signal an alert to workers when gas levels are reaching dangerous concentrations, allowing action to be taken. Our Gasman, and Gas-Pro portables have reliable chlorine sensor options, for single gas monitoring and multi-gas monitoring.

Control panels can be applied to coordinate numerous fixed gas detection devices and provide a trigger for alarm systems.

For more information about gas detection within water and water treatment, or to explore more of Crowcon’s gas detection range, please get in touch.

Gas Hazards in Battery Power Storage

Batteries are effective at reducing power outages since they can also store excess traditional grid energy. The energy stored within batteries can be released whenever a large volume of power is needed, such as during a power failure at a data centre to prevent data being lost, or as a back-up power supply to a hospital or military application to ensure the continuity of vital services. Large scale batteries can also be used to plug short-term gaps in demand from the grid. These battery compositions can also be used in smaller sizes to power electric cars and may be further scaled down to power commercial products, such as phones, tablets, laptops, speakers and – of course – personal gas detectors.

Gas hazards

The main gas risk emitted by batteries, specifically lead acid batteries, is hydrogen. It is possible to get both hydrogen and oxygen evolved during charging however, a lead acid battery is likely to have catalytic recombination parts internally, so oxygen is less of a risk. Hydrogen is always a cause for concern, as it can collect and build up. A situation that is obviously worsened when they are charged in a space with a poor airflow.

When charging, lead-acid batteries consist of lead and oxide at the positive terminal, and of spongy lead at the negative anode, using concentrated sulfuric acid as the electrolyte. The presence of sulfuric acid is another cause for concern if the battery leaks or is ever damaged because concentrated acids harm people, metals and the environment.

When charging batteries also emit oxygen and hydrogen because of the electrolysis process. The levels of hydrogen produced soar when a lead acid battery cell “blows” or is unable to be charged properly. The amount of gas present is relevant because high levels of hydrogen make it highly explosive, even though it is not toxic. Hydrogen has a 100% lower explosive limit of 4.0% by volume, at which level an ignition source would cause fires or for hydrogen more usually, explosions. Fires and explosions are an issue not only for the workers within the space, but also for the surrounding equipment and infrastructure.

Importance of Gas Detection Technology

Gas detection is an invaluable safety technology often equipped in battery charging rooms. Ventilation is also advised, and while helpful, it is not fool proof as fan motors can fail and should not be relied upon as the sole safety measure for battery charging areas. Fans mask the problem while gas detection notifies personnel to act before problems escalate. Gas detection systems are crucial in informing personnel of increasing gas leaks before becoming dangerous. Gas detection units comply with local building codes and NFPA 111, the National Fire Protection Association standard on stored electrical energy emergency and standby power systems. They include maintenance, operation, installation, and testing provisions regarding the system’s performance. In addition to permanent gas detection systems, handheld units are available. The benchmark products are provided by Crowcon and are listed below.

Portable Gas Detectors

Crowcon’s portable gas detectors (Gasman, Gas-Pro, T4x, Tetra 3 and T4) protect against a wide range of industrial gas hazards, with both single gas and multi-gas monitors available. With a wide range of sizes and complexities, you can find the right portable gas detection solution to meet the number and type of gas sensors you need and your display and certification requirements.

Fixed Gas Detectors

Crowcon gas detection fixed systems offer a flexible range of solutions that can measure flammable, toxic, and oxygen gases, report their presence, and activate alarms or associated equipment. Crowcon fixed gas monitoring systems (Xgard, Xgard Bright and XgardIQ) are designed to be interfaced with manual call points, fire and gas detectors, and distributed control systems (DCS).

Control Panels

Crowcon gas detection control panels offer a flexible range of solutions that can measure flammable, toxic, and oxygen gases, report their presence, and activate alarms or associated equipment. Crowcon fixed gas (Vortex, GM Addressable Controllers, Gasmaster) monitoring systems are designed to be interfaced with manual call points, fire and gas detectors and distributed control systems (DCS). In addition, each system can be engineered to drive remote annunciators and mimic panels. Crowcon has a gas detection product to suit your application regardless of your operation.

Temperature Measurement

Crowcon has extensive experience with temperature measurement. There are several models of temperature measurement, from pocket thermometers to industrial kits ranging from -99.9 to 299.9°C with probes and clamps. They are enhancing their fixed detection capabilities by adding high-temperature electrochemical sulphur dioxide detection for battery manufacturing and charging stations. This is critical during the first charge of a battery, as a fault is most likely at that time. Their fast-acting systems detect the precursors to thermal runaway and quickly terminate power to the batteries to avoid damage.

To find out more on the dangers of gas hazards in battery power visit our industry page for more information.

The Importance of Gas Detection in the Power Industry

The energy industry is the very backbone of our industrial and domestic worlds, supplying essential energy to industrial, manufacturing, commercial and residential customers around the globe. With the inclusion of fossil fuel industries (petroleum, coal, LNG); electricity generation, distribution and sales; nuclear energy and renewable energy, the power generation sector is essential in supporting the increasing demand for power from emerging countries and an increasing world population.

Gas Hazards in Power Sector

Gas detection systems have been installed extensively in the power industry to minimise potential consequence through the detection of gas exposure with those working within this industry are exposed to a variation of power plant gas hazards.

Carbon monoxide

The transport and pulverisation of coal poses a high risk of combustion. Fine coal dust becomes suspended in air and highly explosive. The smallest spark, for example from plant equipment, can ignite the dust cloud and cause an explosion that sweeps up more dust, which explodes in turn, and so on in a chain reaction. Coal power plants now require combustible dust certification, in addition to hazardous gas certification.

Coal power plants generate large volumes of carbon monoxide (CO) which is both highly toxic and flammable and must be accurately monitored. A toxic component of incomplete combustion, CO comes from boiler casing leaks and smouldering coal. It is vital to monitor CO in coal tunnels, bunkers, hoppers and tipper rooms, along with infrared-type flammable gas detection to detect pre-fire conditions.

Hydrogen

With hydrogen fuel cells gaining popularity as alternatives to fossil fuel, it is important to be aware of the dangers of hydrogen. Like all fuels, hydrogen is highly flammable and if it leaks there is real risk of fire. Hydrogen burns with a pale blue, almost invisible, flame that can cause serious injuries and severe equipment damage. Therefore, hydrogen must be monitored, to prevent seal-oil system fires, unscheduled shutdowns and to protect personnel from fire.

In addition, power plants must have back-up batteries, to ensure the continued functioning of critical control systems in cases of power outage. Battery rooms generate considerable hydrogen, and monitoring is often carried out in conjunction with ventilation. Traditional lead acid batteries produce hydrogen when they are being charged. These batteries are normally charged together, sometimes in the same room or area, which can generate an explosion risk, especially if the room is not properly ventilated.

Confined Space Entry

Confined space entry (CSE) is often considered to be a dangerous type of work performed in power generation. It is therefore important that the entry is strictly controlled and detailed precautions are taken. Lack of oxygen, toxic and flammable gases are risks that can occur during work in confined spaces, which should never be considered as simple or routine. However, the hazards of working in confined spaces can be predicted, monitored, and mitigated through the use of portable gas detection devices. Confined Spaces Regulations 1997. Approved Code of Practice, Regulations and guidance is for employees that work in Confined Spaces, those who employ or train such people and those who represent them.

Our Solutions

Elimination of these gas hazards is virtually impossible, so permanent workers and contractors must depend on reliable gas detection equipment to protect them. Gas detection can be provided in both fixed and portable forms. Our portable gas detectors protect against a wide range of gas hazards, these include T4x, Gasman, Tetra 3,Gas-Pro, T4, and Detective+. Our fixed gas detectors are used in many applications where reliability, dependability and lack of false alarms are instrumental to efficient and effective gas detection, these include Xgard, Xgard BrightXgardIQ and IRmax. Combined with a variety of our fixed detectors, our gas detection control panels offer a flexible range of solutions that measure flammable, toxic and oxygen gases, report their presence and activate alarms or associated equipment, for the power industry our panels include Vortex and Gasmonitor.

To find out more on the gas hazards in the power industry visit our industry page for more information.

An Introduction to the Oil and Gas Industry 

The oil and gas industry is one of the biggest industries in the world, making a significant contribution to the global economy. This vast sector is often separated into three main sectors: upstream, midstream and downstream. Each sector comes with their own unique gas hazards. 

Upstream

The upstream sector of the oil and gas industry, sometimes referred to as exploration and production (or E&P), is concerned with locating sites for oil and gas extraction the subsequent drilling, recovery and production of crude oil and natural gas. Oil and gas production is an incredibly capital-intensive industry, requiring the use of expensive machinery equipment as well as highly skilled workers. The upstream sector is wide-ranging, encompassing both onshore and offshore drilling operations. 

The major gas hazard encountered in upstream oil and gas is hydrogen sulphide (H2S), a colourless gas known by its distinct rotten egg like smell. H2S is a highly toxic, flammable gas which can have harmful effects on our health, leading to loss of consciousness and even death at high levels. 

Crowcon’s solution for hydrogen sulphide detection comes in the form of the XgardIQ, an intelligent gas detector which increases safety by minimising the time operators must spend in hazardous areas. XgardIQ is available with high-temperature H2S sensor, specifically designed for the harsh environments of the Middle East. 

Midstream

The midstream sector of the oil and gas industry encompasses the storage, transportation and processing of crude oil and natural gas. The transportation of crude oil and natural gas is done by both land and sea with large volumes transported in tankers and marine vessels. On land, transportation methods used are tankers and pipelines. Challenges within the midstream sector include but are not limited to maintaining the integrity of storage and transportation vessels and protecting workers involved in cleaning, purging and filling activities. 

Monitoring of storage tanks is essential to ensure the safety of workers and machinery. 

Downstream

The downstream sector refers to the refining and processing of natural gas and crude oil and the distribution of finished products. This is the stage of the process where these raw materials are transformed into products which are used for a variety of purposes such as fuelling vehicles and heating homes.  

The refining process for crude oil is generally split into three basic steps: separation, conversion and treatment. Natural gas processing involves separating the various hydrocarbons and fluids to produce ‘pipeline quality’ gas. 

The gas hazards which are typical within the downstream sector are hydrogen sulphide, sulphur dioxide, hydrogen and a wide range of toxic gases. Crowcon’s Xgard and Xgard Bright fixed detectors both offer a wide range of sensor options to cover all the gas hazards present in this industry. Xgard Bright is also available with the next generation MPS™ sensor, for the detection of over 15 flammable gases in one detector. Also available are both single and multi-gas personal monitors to ensure workers safety in these potentially hazardous environments. These include the Gas-Pro and T4x, with Gas-Pro providing 5 gas support in a compact and rugged solution.

Why is gas emitted in cement production?

How is cement produced?

Concrete is one of the most important and commonly used materials in global construction. Concrete is widely used in the construction of both residential and commercial buildings, bridges, roads and more. 

The key component of concrete is cement, a binding substance which binds all the other components of concrete (generally gravel and sand) together. More than 4 billion tonnes of cement is used worldwide every year, illustrating the massive scale of the global construction industry. 

Making cement is a complex process, starting with raw materials including limestone and clay which are placed in large kilns of up to 120m in length, which are heated to up to 1,500°C. When heated at such high temperatures, chemical reactions cause these raw materials to come together, forming cement. 

As with many industrial processes, cement production is not without its dangers. The production of cement has the potential to release gases which are harmful to workers, local communities and the environment. 

What gas hazards are present in cement production?

The gases generally emitted in cement plants are carbon dioxide (CO2), nitrous oxides (NOx) and sulphur dioxide (SO2), with CO2 accounting for the majority of emissions. 

The sulphur dioxide present in cement plants generally comes from the raw materials which are used in the cement production process. The main gas hazard to be aware of is carbon dioxide, with the cement making industry responsible for a massive 8% of global CO2 emissions. 

The majority of carbon dioxide emissions are created from a chemical process called calcination. This occurs when limestone is heated in the kilns, causing it to break down into CO2 and calcium oxide.  The other main source of CO2 is the combustion of fossil fuels. The kilns used in cement production are generally heated using natural gas or coal, adding another source of carbon dioxide into addition to that which is generated through calcination. 

Detecting gas in cement production

In an industry which is a large producer of hazardous gases, detection is key. Crowcon offer a wide range of both fixed and portable detection solutions. 

Xgard Bright is our addressable fixed-point gas detector with display, providing ease of operation and reduced installation costs. Xgard Bright has options for the detection of carbon dioxide and sulphur dioxide, the gases of most concern in cement mixing. 

For portable gas detection, the Gasman’s  rugged yet portable and lightweight design make it the perfect single-gas solution for cement production, available in a safe area CO2 version offering 0-5% carbon dioxide measurement. 

For enhanced protection, the Gas-Pro multi-gas detector can be equipped with up to 5 sensors, including all of those most common in cement production, CO2, SO2 and NO2.

The importance of gas detection in the Petrochemical Industry

Closely linked to oil and gas, the petrochemicals industry takes raw materials from refining and gas processing and, through chemical process technologies, converts them into valuable products. In this sector, the organic chemicals produced in the largest volumes are methanol, ethylene, propylene, butadiene, benzene, toluene and xylenes (BTX). These chemicals are the building blocks of many consumer goods including plastics, clothing fabric, construction materials, synthetic detergents and agrichemical products.

Potential Hazards

Exposure to potential hazardous substances is more likely to occur during shutdown or maintenance work as these are a deviation from the refinery’s routine operations. As these deviations are out of normal routine, care should be exercised at all times to avoid the inhalation of solvent vapours, toxic gases, and other respiratory contaminants. The assistance of constant automated monitoring is helpful in determining the presence of solvents or gases, allowing their associated risks to be mitigated. This includes warning systems such as gas and flame detectors, supported by emergency procedures, and permit systems for any kind of potentially dangerous work.

The petroleum industry is split into upstream, midstream and downstream and these are defined by the nature of the work that takes place in each area. Upstream work is typically known as the exploration and production (E&P) sector. Midstream refers to the transportation of products through pipelines, transit and oil tankers as well as the wholesale marketing of petroleum-based products. The downstream sector refers to the refining of petroleum crude oil, the processing of raw natural gas and the marketing and distribution of finished products.

Upstream

Fixed and portable gas detectors are needed to protect plant and personnel from the risks of flammable gas releases (commonly methane) as well as from high levels of H2S, particularly from sour wells. Gas detectors for O2 depletion, SO2 and volatile organic compounds (VOCs) are required items of personal protection equipment (PPE), which is usually highly visible colour and worn near breathing space. Sometimes HF solution is used as a scouring agent. Key requirements for gas detectors are rugged and reliable design and long battery life. Models with design elements that support easy fleet management and compliance obviously have an advantage. You can read about VOC risk and Crowcon’s solution in our case study.

Midstream

Fixed monitoring of flammable gases situated close to pressure relief devices, filling and emptying areas is necessary to deliver early warning of localised leaks. Multi-gas portable monitors must be used to maintain personal safety, especially during work in confined spaces and supporting hot work permit area testing. Infrared technology in flammable gas detection supports purging with the ability to operate in inert atmospheres and delivers reliable detection in areas where pellistor type detectors would fail, due to poisoning or volume level exposure. You can read more on how infrared detection works in our blog and read our case study of infrared monitoring in refinery settings in Southeast Asia.

Portable laser methane detection (LMm) allows users to pin-point leaks at distance and in hard-to-reach areas, reducing the need for personnel to enter potentially dangerous environments or situations while performing routine or investigative leak monitoring. Using LMm is a quick and effective way to check areas for methane with a reflector, from up to 100m away. These areas include closed buildings, confined spaces and other difficult-to-reach areas such as above-ground pipelines that are near water or behind fences.

Downstream

In downstream refining, the gas risks may be almost any hydrocarbon, and may also include hydrogen sulphide, sulphur dioxide and other by-products. Catalytic flammable gas detectors are one of the oldest flammable gas detector types. They work well, but must have a bump testing station, to ensure each detector responds to the target gas and is still functional. The ongoing demand to reduce facility down-time whilst ensuring safety, especially during shutdown and turnaround operations, means that gas detection manufacturers must deliver solutions offering ease of use, straightforward training and reduced maintenance times, along with local service and support.

During plant shutdowns, processes are stopped, items of equipment are opened and checked and the number of people and moving vehicles at the site is many times higher than normal. Many of the processes undertaken will be hazardous and require specific gas monitoring. For example, welding and tank cleaning activities require area monitors as well as personal monitors to protect those on site.

Confined space

Hydrogen sulphide (H2S) is a potential problem in the transport and storage of crude oil. The cleaning of storage tanks presents a high hazard potential. Many confined-space entry problems can occur here, including oxygen deficiency resulting from previous inerting procedures, rusting, and oxidation of organic coatings. Inerting is the process of reducing the oxygen levels in a cargo tank to remove the oxygen element required for ignition. Carbon monoxide can be present in the inerting gas. In addition to H2S, depending on the characteristics of the product previously stored in the tanks, other chemicals that may be encountered include metal carbonyls, arsenic, and tetraethyl lead.

Our Solutions

Elimination of these gas hazards is virtually impossible, so permanent workers and contractors must depend on reliable gas detection equipment to protect them. Gas detection can be provided in both fixed and portable forms. Our portable gas detectors protect against a wide range of gas hazards, these include Clip SGD, Gasman, Tetra 3,Gas-Pro, T4, Gas-Pro TK and Detective+. Our fixed gas detectors are used in many applications where reliability, dependability and lack of false alarms are instrumental to efficient and effective gas detection, these include Xgard, Xgard Bright, Fgard IR3 Flame Detector and IRmax. Combined with a variety of our fixed detectors, our gas detection control panels offer a flexible range of solutions that measure flammable, toxic and oxygen gases, report their presence and activate alarms or associated equipment, for the petrochemical industry our panels include Addressable Controllers, Vortex and Gasmonitor.

To find out more on the gas hazards in the petrochemical industry visit our industry page for more information.

The importance of Gas Detection in the Water and Wastewater Industry 

Water is vital to our daily lives, both for personal and domestic use and industrial/commercial applications. Whether a facility focuses on the production of clean, potable water or treating effluent, Crowcon is proud to serve a wide variety of water industry clients, providing gas detection equipment that keeps workers safe around the world. 

Gas Hazards 

Apart from common gas hazards known in the industry; methane, hydrogen sulphide, and oxygen, there are bi-product gas hazards and cleaning material gas hazards that occur from purifying chemicals such as ammonia, chlorine, chlorine dioxide or ozone that are used in the decontamination of the waste and effluent water, or to remove microbes from clean water. There is great potential for many toxic or explosive gases to exist as a result of the chemicals used in the water industry. And added to these are chemicals that may be spilled or dumped into the waste system from industry, farming or building work. 

Safety Considerations  

Confined Space Entry 

The pipelines used to transport water require regular cleaning and safety checks; during these operations, portable multi-gas monitors are used to protect the workforce. Pre-entry checks must be completed prior to entering any confined space and commonly O2, CO, H2S and CH4 are monitored. Confined spaces are small, so portable monitors must be compact and unobtrusive for the user, yet able to withstand the wet and dirty environments in which they must perform. Clear and prompt indication of any increase in gas monitored (or any decrease for oxygen) is of paramount importance – loud and bright alarms are effective in raising the alarm to the user. 

Risk assessment 

Risk assessment is critical, as you need to be aware of the environment that you are entering and thus working in. Therefore, understanding the applications and identifying the risks regarding all safety aspects. Focusing on gas monitoring, as part of the risk assessment, you need to be clear on what gases may be present.  

Fit for purpose 

There is a variety of applications within the water treatment process, giving the need to monitor multiple gases, including carbon dioxide, hydrogen sulphide, chlorine, methane, oxygen, ozone and chlorine dioxide. Gas detectors are available for single or multiple gas monitoring, making them practical for different applications as well as making sure that, if conditions change (such as sludge is stirred up, causing a sudden increase in hydrogen sulphide and flammable gas levels), the worker is still protected.  

Legislation   

European Commission Directive 2017/164 issued in January 2017, established a new list of indicative occupational exposure limit values (IOELVs). IOELV are health-based, non-binding values, derived from the most recent scientific data available and considering the availability of reliable measurement techniques. The list includes carbon monoxide, nitrogen monoxide, nitrogen dioxide, sulphur dioxide, hydrogen cyanide, manganese, diacetyl and many other chemicals. The list is based on Council Directive 98/24/EC that considers the protection of the health and safety of workers from the risks related to chemical agents in the workplace. For any chemical agent for which an IOELV has been set at Union level, Member States are required to establish a national occupational exposure limit value. They also are required to take into account the Union limit value, determining the nature of the national limit value in accordance with national legislation and practice. Member States will be able to benefit from a transitional period ending at the latest on 21 August 2023.  

The Health and Safety Executive (HSE) state that each year several workers will suffer from at least one episode of work-related illness. Although, most illnesses are relatively mild cases of gastroenteritis, there is also a risk for potentially fatal diseases, such as leptospirosis (Weil’s disease) and hepatitis. Even though these are reported to the HSE, there could be significant under-reporting as there is often failure to recognise the link between illness and work.  

Under domestic law of the Health and Safety at Work etc Act 1974, employers are responsible for ensuring the safety of their employees and others. This responsibility is reinforced by regulations. 

The Confined Spaces Regulations 1997 applies where the assessment identifies risks of serious injury from work in confined spaces. These regulations contain the following key duties: 

  • Avoid entry to confined spaces, e.g., by doing the work from the outside. 
  • If entry to a confined space is unavoidable, follow a safe system of work.
  • Put in place adequate emergency arrangements before the work start. 

The Management of Health and Safety at Work Regulations 1999 requires employers and self-employed people to carry out a suitable and sufficient assessment of the risks for all work activities for the purpose of deciding what measures are necessary for safety. For work in confined spaces this means identifying the hazards present, assessing the risks and determining what precautions to take. 

Our solutions

Elimination of these gas hazards is virtually impossible, so permanent workers and contractors must depend on reliable gas detection equipment to protect them. Gas detection can be provided in both fixed and portable forms. Our portable gas detectors protect against a wide range of gas hazards, these include T4x, Clip SGD, Gasman, Tetra 3,Gas-Pro, T4 and Detective+. Our fixed gas detectors are used in many applications where reliability, dependability and lack of false alarms are instrumental to efficient and effective gas detection, these include Xgard, Xgard Bright and IRmax. Combined with a variety of our fixed detectors, our gas detection control panels offer a flexible range of solutions that measure flammable, toxic and oxygen gases, report their presence and activate alarms or associated equipment, for the wastewater industry our panels include  Gasmaster.    

To find out more on the gas hazards in wastewater and water treatment visit our industry page for more information.  

The Dangers of Gas in Farming and Agriculture 

Farming and agriculture is a colossal industry the world over, providing more than 44 million jobs in the EU and making up over 10% of total US employment. 

With a wide range of processes involved in this sector, there are bound to be hazards that must be considered. These include gas hazards from the likes of methane, hydrogen sulphide, ammonia, carbon dioxide and nitrous oxide. 

Methane is a colourless, odourless gas which can have harmful effects on humans resulting in slurred speech, vision problems, memory loss, nausea and in extreme cases can impact breathing and heartrate, potentially leading to unconsciousness and even death. In agricultural environments, it is created through anaerobic digestion of organic material, such as manure. The amount of methane generated is exacerbated in areas which are poorly ventilated or high in temperature, and in areas with particular lack of airflow, the gas can build up, become trapped and cause explosions. 

Carbon dioxide (CO2) is a gas which is naturally produced in the atmosphere, levels of which can be heightened by agricultural processes. CO2 can be emitted by a range of farming process including crop and livestock production and is also emitted by some equipment which is used in agricultural applications. Storage spaces used for waste and grain and sealed silos are of particular concern due to the capacity for CO2 to build up and displace oxygen, increasing suffocation risk for both animals and humans alike. 

Similarly, to methane, hydrogen sulphide comes from the anaerobic decomposition of organic material and can also be found in a range of agricultural processes relating to the production and consumption of biogas. H2S prevents oxygen from being carried to our vital organs and areas where it builds up often have reduced oxygen concentrations, furthering the risk of asphyxiation where H2S levels are high. Whilst it could be considered easier to detect due its distinct ‘rotten egg’ smell, the intensity of the smell actually decreases at higher concentrations and prolonged exposure. At high levels, H2S can cause severe irritation of, and fluid build-up in the lungs and impact the nervous system. 

Ammonia (NH3) is a gas found in animal waste which is often then spread and emitted further through slurry spreading on agricultural land. As with many of the gases covered, the impact of ammonia is heightened when there is a lack of ventilation. It is harmful to the wellbeing of both livestock and humans, causing respiratory diseases in animals whilst high levels can lead to burns and swelling of the airways and lung damage in humans and can be fatal. 

Nitrogen oxide (NO2) is another gas to be aware of in the agriculture and farming industry. It is present in synthetic fertilisers which are often used in more intensive farming practices to ensure greater crop yields. The potential negative health impacts of NO2 in humans include reduced lung function, internal bleeding, and ongoing respiratory problems.  

Workers in this industry are frequently on the move, and for this specific purpose Crowcon offers a wide range of fixed and portable gas detectors to keep workers safe. Crowcon’s portable range comprises T4, Gas-Pro, Clip SGD and Gasman all of which offer reliable, transportable detection capacities for a variety of gases. Our fixed gas detectors are used where reliability, dependability and lack of false alarms are instrumental to efficient and effective protection of assets and areas, and include the Xgard and Xgard Bright. Combined with a variety of our fixed detectors, our gas detection control panels offer a flexible range of solutions that measure flammable, toxic and oxygen gases, report their presence and activate alarms or associated equipment, for the farming and agriculture industry we often recommend our Gasmaster, Vortex and Addressable Controllers panels.

To find out more on the gas hazards in farming and agriculture visit our industry page for more information.

An Introduction to the Marine Industry

The marine sector is a global industry and is wide ranging in terms of its applications and different types of vessels including FPSO vessels, ferries and submarines. 

The type of gas hazards that will be present, and subsequently the gas detection requirements, are heavily dependent on the application and the type of marine vessel being used. In this blog we’ll take a look at some of the most common gas hazards within the marine industry and in which applications they are most likely to occur. 

Floating Production, Storage, Offloading Units and Tankers 

Floating production, storage and offloading (FPSO) units, which are used in the production, processing and storage of oil, are home to many potential gas hazards. 

Firstly, there is the risk of fire and explosion hazards, which can lead to catastrophic damage and loss of life.  Combustible gas risks that may be present include methane, hydrogen, propane, LPG, solvents and gasoline fumes among others. Due to this risk, flammable gas detection is essential on FPSO vessels.  

FPSO units also have confined spaces in the form of inverted tanks or voids, meaning oxygen detectors are a must for these areas to protect from the risks of oxygen depletion which can cause mental confusion, nausea, weakness and in extreme cases loss of consciousness and death. 

Ferries 

Whilst ferries may not be home to as many gas hazards as other vessels, there are certainly still some to be aware of. On vehicle carrying ferries, for example, there may be a large build-up of emissions from vehicle exhausts which contain harmful gases such as carbon monoxide and nitrogen dioxide. Both gases are capable of causing damage to human health, causing issues such as nausea, confusion and disorientation, inflammation of the airways and increased vulnerability to respiratory infection. 

Submarines 

Submarines may be used for a variety of purposes including salvage and exploration operations, marine science and facility inspection and maintenance. On these vessels there may be a requirement for hydrogen detection in battery storage rooms. Whilst hydrogen is a non-toxic gas, if it builds up in environments without sufficient airflow it can displace oxygen in the air leading to risk of oxygen depletion. 

Our solutions 

Gas detection can be provided in both fixed and portable forms. Our portable gas detectors protect people against a wide range of gas hazards, and include T4xGas-ProT4 and Gas-Pro TK. Our fixed gas detectors are used where reliability, dependability and lack of false alarms are instrumental to efficient and effective protection of assets and areas. Now available through Crowcon, the Sensitron SMART S-MS MED fixed detector has been designed specifically for use in marine environments. The SMART S-MS MED is fully marine certified by Lloyd’s Register in accordance with MED/3.54 Regulation whilst also being SIL-2 certified. Also available is the Multiscan++MED control panel, also MED and SIL-2 certified, able to manage and monitor up to 64 gas detectors. 

To find out more on the gas hazards in the marine sector visit our industry page for more information.

Gas Safety Protocols in Water Treatment

Water is vital to our daily lives, both for personal and domestic use and industrial/commercial applications. It is everywhere, promoting some chemical reactions and inhibiting others. Being used to clean surfaces, carry chemicals to where they are used and to carry unwanted chemicals away. Do anything and you create a gas somewhere in some quantity. Do anything with water there are so many permutations of things that can come together and react, dissolved gases that can come out of solution, dissolved liquids and solids that can react to generate gases. Additionally, you must determine what gases you generate when you collect, clean, store, transport or use water. Gas detectors must be chosen to suit the specific environment in which they operate, in this case highly humid, often dirty, but rarely outside the temperature range 4 to 30 degrees C. All the risks are present in these complex environments, with multiple toxic and flammable gas hazards and often the additional risk of oxygen depletion.

Gas Hazards

Apart from common gas hazards known in the industry; methane, hydrogen sulphide, and oxygen, there are bi-product gas hazards and cleaning material gas hazards that occur from purifying chemicals such as ammonia, chlorine, chlorine dioxide or ozone that are used in the decontamination of the waste and effluent water, or to remove microbes from clean water. There is great potential for many toxic or explosive gases to exist as a result of the chemicals used in the water industry. And added to these are chemicals that may be spilled or dumped into the waste system from industry, farming or building work.

Chlorine (Cl2) gas appears yellow green in colour, used to sterilise drinking water. However, most chlorine is used in the chemical industry with typical applications including water treatment as well as within the plastics and cleaning agents. Chlorine gas can be recognised by its pungent, irritating odour, which is like the odour of bleach. The strong smell may provide adequate warning to people that they are exposed. Cl2 itself is not flammable, but it can react explosively or form flammable compounds with other chemicals such as turpentine and ammonia.

Ammonia (NH3) is a compound of nitrogen and hydrogen and is a colourless and pungent gas, also known to be highly soluble when in contact with water. This means that NH3 dissolves quickly into the water supply. Found at very low levels in humans and in nature. It is also often used in some household cleaning solutions. Although NH3 has many benefits, it can be corrosive and dangerous in certain circumstances. Ammonia can enter wastewater from several different sources, including urine, manure, cleaning chemicals, process chemicals and amino acid products. If NH3 enters a copper piping system, it can cause extensive corrosion. If NH3 enters water, its toxicity varies depending on the exact pH of the water. It is possible for ammonia to break down into ammonium ions, which can react with other compounds present.

Chlorine dioxide (ClO2) is an oxidising gas commonly used to disinfect drinking water. When used in very small quantities, it is safe and does not lead to significant health risks. But ClO2 is a strong disinfectant that kills bacteria, viruses, and fungi, and when used in high doses, it can be dangerous to people since it can damage red blood cells and the lining of the gastrointestinal (GI) tract.

Ozone (O3) is a gas with an antiseptic smell and no colour that, mostly, forms naturally in the environment. When inhaled, ozone can have a range of harmful effects on the body. As it is colourless gas it is difficult to trace without an effective detection system in place. Even when relatively small amounts are inhaled, the gas can have a damaging impact on the respiratory tract, causing inflammation and chest pain, alongside coughing, shortness of breath and throat irritation. It can also act as a trigger causing diseases such as asthma to worsen.

Confined Space Entry

The pipelines used to transport water require regular cleaning and safety checks; during these operations, portable multi-gas monitors are used to protect the workforce. Pre-entry checks must be completed prior to entering any confined space and commonly O2, CO, H2S and CH4 are monitored. Confined spaces are small, so portable monitors must be compact and unobtrusive for the user, yet able to withstand the wet and dirty environments in which they must perform. Clear and prompt indication of any increase in gas monitored (or any decrease for oxygen) is of paramount importance – loud and bright alarms are effective in raising the alarm to the user.

Legislation

European Commission Directive 2017/164 established an increased list of indicative occupational exposure limit values (IOELVs). IOELV are health-based, non-binding values, derived from the most recent scientific data available and considering the availability of reliable measurement techniques. Non-binding but best practice. The list includes carbon monoxide, nitrogen monoxide, nitrogen dioxide, sulphur dioxide, hydrogen cyanide, manganese, diacetyl and many other chemicals. The list is based on Council Directive 98/24/EC that considers the protection of the health and safety of workers from the risks related to chemical agents in the workplace. For any chemical agent for which an IOELV has been set at Union level, Member States are required to establish a national occupational exposure limit value. They also are required to take into account the Union limit value, determining the nature of the national limit value in accordance with national legislation and practice. Member States will be able to benefit from a transitional period ending at the latest on 21 August 2023.

The Health and Safety Executive (HSE) state that each year several workers will suffer from at least one episode of work-related illness. Although, most illnesses are relatively mild cases of gastroenteritis, there is also a risk for potentially fatal diseases, such as leptospirosis (Weil’s disease) and hepatitis. Even though these are reported to the HSE, there could be significant under-reporting as there is often failure to recognise the link between illness and work.

Under domestic law of the Health and Safety at Work etc Act 1974, employers are responsible for ensuring the safety of their employees and others. This responsibility is reinforced by regulations.

The Confined Spaces Regulations 1997 applies where the assessment identifies risks of serious injury from work in confined spaces. These regulations contain the following key duties:

  • Avoid entry to confined spaces, e.g., by doing the work from the outside.
  • If entry to a confined space is unavoidable, follow a safe system of work.
  • Put in place adequate emergency arrangements before the work start.

The Management of Health and Safety at Work Regulations 1999 requires employers and self-employed people to carry out a suitable and sufficient assessment of the risks for all work activities for the purpose of deciding what measures are necessary for safety. For work in confined spaces this means identifying the hazards present, assessing the risks and determining what precautions to take.

Our solution

Elimination of these gas hazards is virtually impossible, so permanent workers and contractors must depend on reliable gas detection equipment to protect them. Gas detection can be provided in both fixed and portable forms. Our portable gas detectors protect people against a wide range of gas hazards, and include T4x, Clip SGD, Gasman, Tetra 3, Gas-Pro, T4 and Detective+. Our fixed gas detectors are used where reliability, dependability and lack of false alarms are instrumental to efficient and effective protection of assets and areas, and include the Xgard, Xgard Bright and IRmax product ranges. Combined with a variety of our fixed detectors, our gas detection control panels offer a flexible range of solutions that measure flammable, toxic and oxygen gases, report their presence and activate alarms or associated equipment, for the wastewater industry we often recommend our Gasmaster panel.

To find out more on the gas hazards in wastewater visit our industry page for more information.