Why is gas emitted in cement production?

How is cement produced?

Concrete is one of the most important and commonly used materials in global construction. Concrete is widely used in the construction of both residential and commercial buildings, bridges, roads and more.

The key component of concrete is cement, a binding substance which binds all the other components of concrete (generally gravel and sand) together. More than 4 billion tonnes of cement is used worldwide every year, illustrating the massive scale of the global construction industry.

Making cement is a complex process, starting with raw materials including limestone and clay which are placed in large kilns of up to 120m in length, which are heated to up to 1,500°C. When heated at such high temperatures, chemical reactions cause these raw materials to come together, forming cement.

As with many industrial processes, cement production is not without its dangers. The production of cement has the potential to release gases which are harmful to workers, local communities and the environment.

What gas hazards are present in cement production?

The gases generally emitted in cement plants are carbon dioxide (CO₂), nitrous oxides (NOx) and sulphur dioxide (SO₂), with CO₂ accounting for the majority of emissions.

The sulphur dioxide present in cement plants generally comes from the raw materials which are used in the cement production process. The main gas hazard to be aware of is carbon dioxide, with the cement making industry responsible for a massive 8% of global CO₂ emissions.

The majority of carbon dioxide emissions are created from a chemical process called calcination. This occurs when limestone is heated in the kilns, causing it to break down into CO₂ and calcium oxide. The other main source of CO₂ is the combustion of fossil fuels. The kilns used in cement production are generally heated using natural gas or coal, adding another source of carbon dioxide into addition to that which is generated through calcination.

Detecting gas in cement production

In an industry which is a large producer of hazardous gases, detection is key. Crowcon offer a wide range of both fixed and portable detection solutions.

Xgard Bright is our addressable fixed-point gas detector with display, providing ease of operation and reduced installation costs. Xgard Bright has options for the detection of carbon dioxide and sulphur dioxide, the gases of most concern in cement mixing.

For portable gas detection, the Gasman’s rugged yet portable and lightweight design make it the perfect single-gas solution for cement production, available in a safe area CO₂ version offering 0-5% carbon dioxide measurement.

For enhanced protection, the Gas-Pro multi-gas detector can be equipped with up to 5 sensors, including all of those most common in cement production, CO₂, SO₂ and NO₂.

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Car Parks are More Dangerous Than You Think

Road vehicles can emit a number of harmful gases through exhaust fumes, the most common being carbon monoxide (CO) and nitrogen dioxide (NO₂). Whilst these cause gases are an issue in open air environments, there is particular cause for concern in more confined spaces such as underground and multi-storey car parks.

Why are car parks of specific concern?

The gases emitted through exhaust fumes are absolutely an issue regardless of where they are being emitted, and contribute to a wide variety of issues including air pollution. However, in car parks any dangers these gases cause are exasperated due to the high number of vehicles in a small, confined area and the lack of natural ventilation to ensure that these gases do not reach dangerous levels.

What gases are present in car parks?

Vehicles emit a variety of exhaust gases including carbon dioxide, carbon monoxide, nitrogen dioxide and sulphur dioxide. Carbon monoxide and nitrogen dioxide are the most common and are also of particular concern due to the potential negative impacts on human health that exposure to these gases can have.

What are the dangers of gases in car parks?

Out of the two most common gases in car parks, carbon monoxide poses the more significant threat to human health. It is an odourless, colourless and tasteless gas making it almost impossible to detect without some sort of detection equipment.

Carbon monoxide is dangerous as it negatively impacts the transport of oxygen around the body which can cause a wide range of health problems. Breathing low levels of CO can cause nausea, dizziness, headaches, confusion and disorientation. Regularly breathing low levels of CO may cause more permanent health issues. At very high levels carbon monoxide can cause loss of consciousness and even death, with around 60 deaths attributed to carbon monoxide poisoning in England and Wales every year.

Breathing in nitrogen dioxide also has negative health impacts including breathing and respiratory issues as well as damage to lung tissue. Exposure to high concentrations can cause inflammation of the airways and prolonged exposure can lead to irreversible damage to the respiratory system

What regulations are there?

In 2015, a new European Standard (EN 50545-1) was introduced, specifically relating to the detection of toxic gases such as CO and NO₂ in car parks and tunnels. EN 50545-1 specifies requirements for remote gas detectors and control panels to be used in car parks. The goal of the standard is to increase the safety of gas detection systems in car parks and prevent the use of inadequate systems. Th standard also the alarm levels to be used for gas detection in car parks, shown in the table below.

	Alarm 1	Alarm 2	Alarm 3
CO	30 ppm	60 ppm	150 ppm
NO₂	3 ppm	6 ppm	15 ppm

Crowcon Park System

Crowcon have recently launched a new range of fixed detectors and control panels designed specifically for gas detection in car parks.

The SMART P set of detectors, consisting of the SMART P-1 and SMART P-2 can detect CO, NO₂ and petrol vapours, with the SMART P-2 offering simultaneous detection of both CO and NO₂ in a single detector. The MULTISCAN++PK control panel can manage and monitor up to 256 detectors. Every product in the range has been designed to fulfil the requirements of the European Standard EN 50545-1.

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The importance of gas detection in the Petrochemical Industry

Closely linked to oil and gas, the petrochemicals industry takes raw materials from refining and gas processing and, through chemical process technologies, converts them into valuable products. In this sector, the organic chemicals produced in the largest volumes are methanol, ethylene, propylene, butadiene, benzene, toluene and xylenes (BTX). These chemicals are the building blocks of many consumer goods including plastics, clothing fabric, construction materials, synthetic detergents and agrichemical products.

Potential Hazards

Exposure to potential hazardous substances is more likely to occur during shutdown or maintenance work as these are a deviation from the refinery’s routine operations. As these deviations are out of normal routine, care should be exercised at all times to avoid the inhalation of solvent vapours, toxic gases, and other respiratory contaminants. The assistance of constant automated monitoring is helpful in determining the presence of solvents or gases, allowing their associated risks to be mitigated. This includes warning systems such as gas and flame detectors, supported by emergency procedures, and permit systems for any kind of potentially dangerous work.

The petroleum industry is split into upstream, midstream and downstream and these are defined by the nature of the work that takes place in each area. Upstream work is typically known as the exploration and production (E&P) sector. Midstream refers to the transportation of products through pipelines, transit and oil tankers as well as the wholesale marketing of petroleum-based products. The downstream sector refers to the refining of petroleum crude oil, the processing of raw natural gas and the marketing and distribution of finished products.

Upstream

Fixed and portable gas detectors are needed to protect plant and personnel from the risks of flammable gas releases (commonly methane) as well as from high levels of H₂S, particularly from sour wells. Gas detectors for O₂ depletion, SO₂ and volatile organic compounds (VOCs) are required items of personal protection equipment (PPE), which is usually highly visible colour and worn near breathing space. Sometimes HF solution is used as a scouring agent. Key requirements for gas detectors are rugged and reliable design and long battery life. Models with design elements that support easy fleet management and compliance obviously have an advantage. You can read about VOC risk and Crowcon’s solution in our case study.

Midstream

Fixed monitoring of flammable gases situated close to pressure relief devices, filling and emptying areas is necessary to deliver early warning of localised leaks. Multi-gas portable monitors must be used to maintain personal safety, especially during work in confined spaces and supporting hot work permit area testing. Infrared technology in flammable gas detection supports purging with the ability to operate in inert atmospheres and delivers reliable detection in areas where pellistor type detectors would fail, due to poisoning or volume level exposure. You can read more on how infrared detection works in our blog and read our case study of infrared monitoring in refinery settings in Southeast Asia.

Portable laser methane detection (LMm) allows users to pin-point leaks at distance and in hard-to-reach areas, reducing the need for personnel to enter potentially dangerous environments or situations while performing routine or investigative leak monitoring. Using LMm is a quick and effective way to check areas for methane with a reflector, from up to 100m away. These areas include closed buildings, confined spaces and other difficult-to-reach areas such as above-ground pipelines that are near water or behind fences.

Downstream

In downstream refining, the gas risks may be almost any hydrocarbon, and may also include hydrogen sulphide, sulphur dioxide and other by-products. Catalytic flammable gas detectors are one of the oldest flammable gas detector types. They work well, but must have a bump testing station, to ensure each detector responds to the target gas and is still functional. The ongoing demand to reduce facility down-time whilst ensuring safety, especially during shutdown and turnaround operations, means that gas detection manufacturers must deliver solutions offering ease of use, straightforward training and reduced maintenance times, along with local service and support.

During plant shutdowns, processes are stopped, items of equipment are opened and checked and the number of people and moving vehicles at the site is many times higher than normal. Many of the processes undertaken will be hazardous and require specific gas monitoring. For example, welding and tank cleaning activities require area monitors as well as personal monitors to protect those on site.

Confined space

Hydrogen sulphide (H₂S) is a potential problem in the transport and storage of crude oil. The cleaning of storage tanks presents a high hazard potential. Many confined-space entry problems can occur here, including oxygen deficiency resulting from previous inerting procedures, rusting, and oxidation of organic coatings. Inerting is the process of reducing the oxygen levels in a cargo tank to remove the oxygen element required for ignition. Carbon monoxide can be present in the inerting gas. In addition to H₂S, depending on the characteristics of the product previously stored in the tanks, other chemicals that may be encountered include metal carbonyls, arsenic, and tetraethyl lead.

Our Solutions

Elimination of these gas hazards is virtually impossible, so permanent workers and contractors must depend on reliable gas detection equipment to protect them. Gas detection can be provided in both fixed and portable forms. Our portable gas detectors protect against a wide range of gas hazards, these include Clip SGD, Gasman, Tetra 3, Gas-Pro, T4, Gas-Pro TK and Detective+. Our fixed gas detectors are used in many applications where reliability, dependability and lack of false alarms are instrumental to efficient and effective gas detection, these include Xgard, Xgard Bright, Fgard IR3 Flame Detector and IRmax. Combined with a variety of our fixed detectors, our gas detection control panels offer a flexible range of solutions that measure flammable, toxic and oxygen gases, report their presence and activate alarms or associated equipment, for the petrochemical industry our panels include Addressable Controllers, Vortex and Gasmonitor.

To find out more on the gas hazards in the petrochemical industry visit our industry page for more information.

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The importance of gas detection in the Medical and Healthcare sector

The need for gas detection in the medical and healthcare sector may be less widely understood outside of the industry, but the requirement is there, nonetheless. With patients across a number of settings receiving a variety of treatment and medical therapies that involve the usage of chemicals, the need to accurately monitor the gases utilised or emitted, within this process is very important to allow for their continued safe treatment. In order to safeguard both patients and, of course, the healthcare professionals themselves, the implementation of accurate and reliable monitoring equipment is a must.

Applications

In healthcare and hospital settings, a range of potentially hazardous gases can present themselves due to the medical equipment and apparatus utilised. Harmful chemicals are also used for disinfectant and cleansing purposes within hospital work surfaces and medical supplies. For example, potentially hazardous chemicals can be used as a preservative for tissue specimens, such as toluene, xylene or formaldehyde. Applications include:

Breath gas monitoring
Chiller rooms
Generators
Laboratories
Storage rooms
Operating theatres
Pre-hospital rescue
Positive airway pressure therapy
High flow nasal cannula therapy
Intensive care units
Post anaesthesia care unit

Gaz Hazards

Oxygen Enrichment in Hospital Wards

In light of the worldwide pandemic, COVID-19, the need for increased oxygen on hospital wards has been recognised by healthcare professionals due to the escalating number of ventilators in use. Oxygen sensors are vital, within ICU wards specifically, as they inform the clinician how much oxygen is being delivered to the patient during ventilation. This can prevent the risk of hypoxia, hypoxemia or oxygen toxicity. If oxygen sensors do not function as they should; they can alarm regularly, need changing and unfortunately even lead to fatalities. This increased use of ventilators also enriches the air with oxygen and can raise the combustion risk. There is a need to measure the levels of oxygen in the air using a fixed gas detection system to avoid unsafe levels in the air.

Carbon Dioxide

Carbon dioxide level monitoring is also required in healthcare environments to ensure a safe working environment for professionals, as well as to safeguard patients being treated. Carbon dioxide is used within a plethora of medical and healthcare procedures from minimally invasive surgeries, such as endoscopy, arthroscopy and laparoscopy, cryotherapy and anaesthesia. CO₂ is also used in incubators and laboratories and, as it is a toxic gas, can cause asphyxiation. Heightened levels of CO₂ in the air, emitted by certain machinery, can cause harm to those in the environment, as well as spread pathogens and viruses. CO₂ detectors in healthcare environments can therefore improve ventilation, air flow and the wellbeing of all.

Volatile Organic Compounds (VOCs)

A range of VOCs can be found in hospital and healthcare environments and cause harm to those working and being treated within it. VOCs such as aliphatic, aromatic and halogenated hydrocarbons, aldehydes, alcohols, ketones, ethers and terpenes, to name a few, have been measured in hospital environments, originating from a number of specific areas including reception halls, patient rooms, nursing care, post-anaesthesia care units, parasitology-mycology labs and disinfection units. Although still in the research stage of their prevalence in healthcare settings, it is clear VOC ingestion has adverse effects on human health such as irritation to the eyes, nose, and throat; headaches and the loss of coordination; nausea; and damage to the liver, kidneys, or central nervous system. Some VOCs, benzene specifically, is a carcinogen. Implementing gas detection is therefore a must to safeguard everyone from harm.

Gas sensors should therefore be used within PACU, ICU, EMS, pre-hospital rescue, PAP therapy and HFNC therapy to monitor the gas levels of a range of equipment including ventilators, oxygen concentrators, oxygen generators and anaesthesia machines.

Standards and Certifications

The Care Quality Commission (CQC) is the organisation in England that regulates the quality and safety of the care delivered within all healthcare, medical, health and social care, and voluntary care settings across the country. The commission provides best practice details for the administering of oxygen to patients and the proper measurement and recording of levels, storage and training about the use of this and other medical gases.

The UK regulator for medical gases is the Medicines and Healthcare products Regulatory Agency (MHRA). They are an Executive Agency of the Department of Health and Social Care (DHSC) that ensures public and patient health and safety through the regulation of medicines, healthcare products and medical equipment in the sector. They set appropriate standards of safety, quality, performance and effectiveness, and ensure all equipment is used safely. Any company manufacturing medical gases requires a Manufacturer’s Authorisation issued by the MHRA.

In the USA The Food and Drug Association (FDA) regulates the certification process for the manufacture, sale and marketing of designated medical gases. Under Section 575 the FDA states that anyone marketing a medical gas for human or animal drug use without an approved application is breaking specified guidelines. The medical gases that require certification include oxygen, nitrogen, nitrous oxide, carbon dioxide, helium, 20 carbon monoxide, and medical air.

To find out more on the dangers in the medial and healthcare sector, visit our industry page for more information.

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Why is gas detection crucial for drink dispense systems

Dispense gas known as beer gas, keg gas, cellar gas or pub gas is used in bars and restaurants as well as the leisure and hospitality industry. Using dispense gas in the process of dispensing beer and soft drinks is common practice worldwide. Carbon dioxide (CO₂) or a mix of CO₂ and nitrogen (N₂) is used as a way of delivering a beverage to the ‘tap’. CO₂as a keg gas helps to keep the contents sterile and at the right composition aiding dispensing.

Gas Hazards

Even when the beverage is ready to deliver, gas-related hazards remain. Those arise in any activity at premises that contain compressed gas cylinders, due to the risk of damage during their movement or replacement. Additionally, once released there is a risk of increased carbon dioxide levels or depleted oxygen levels (due to higher levels of nitrogen or carbon dioxide).

CO₂occurs naturally in the atmosphere (0.04%) and is colourless and odourless. It is heavier than air and if it escapes, will tend to sink to the floor. CO₂ collects in cellars and at the bottom of containers and confined spaces such as tanks and silos. CO₂ is generated in large amounts during fermentation. It is also injected into beverages during carbonation – to add the bubbles. Early symptoms of exposure to high levels of carbon dioxide include dizziness, headaches, and confusion, followed by loss of consciousness. Accidents and fatalities can occur in extreme cases where a significant amount of carbon dioxide leaks into an enclosed or poorly ventilated volume. Without proper detection methods and processes in place, everyone entering that volume could be at risk. Additionally, personnel within surrounding volumes could suffer from the early symptoms listed above.

Nitrogen (N₂) is often used in the dispensing of beer, particularly stouts, pale ales and porters, it also as well as preventing oxidisation or pollution of beer with harsh flavours. Nitrogen helps push the liquid from one tank to another, as well as offer the potential to be injected into kegs or barrels, pressurising them ready for storage and shipment. This gas is not toxic, but does displace oxygen in the atmosphere, which can be a danger if there is a gas leak which is why accurate gas detection is critical.

As nitrogen can deplete oxygen levels, oxygen sensors should be used in environments where any of these potential risks exist. When locating oxygen sensors, consideration needs to be given to the density of the diluting gas and the “breathing” zone (nose level). Ventilation patterns must also be considered when locating sensors. For example, if the diluting gas is nitrogen, then placing the detection at shoulder height is reasonable, however if the diluting gas is carbon dioxide, then the detectors should be placed at knee height.

The Importance of Gas Detection in Drinks Dispense Systems

Unfortunately, accidents and fatalities do occur in the drinks industry due to gas hazards. As a result, in the UK, safe workplace exposure limits are codified by the Health and Safety Executive (HSE) in documentation for the Control of Substances Hazardous to Health (COSHH). Carbon dioxide has an 8-hour exposure limit of 0.5% and a 15-minute exposure limit of 1.5% by volume. Gas detection systems help to mitigate gas risks and allow for drinks manufacturers, bottling plants and bar/pub cellar owners, to ensure the safety of personnel and demonstrate compliance to legislative limits or approved codes of practice.

Oxygen Depletion

The normal concentration of oxygen in the atmosphere is approximately 20.9% volume. Oxygen levels can be dangerous if they are too low (oxygen depletion). In the absence of adequate ventilation, the level of oxygen can be reduced surprisingly quickly by breathing and combustion processes.

Oxygen levels may also be depleted due to dilution by other gases such as carbon dioxide (also a toxic gas), nitrogen or helium, and chemical absorption by corrosion processes and similar reactions. Oxygen sensors should be used in environments where any of these potential risks exist. When locating oxygen sensors, consideration needs to be given to the density of the diluting gas and the “breathing” zone (nose level). Oxygen monitors usually provide a first-level alarm when the oxygen concentration has dropped to 19% volume. Most people will begin to behave abnormally when the level reaches 17%, and hence a second alarm is usually set at this threshold. Exposure to atmospheres containing between 10% and 13% oxygen can bring about unconsciousness very rapidly; death comes very quickly if the oxygen level drops below 6% volume.

Our Solution

Gas detection can be provided in the form of both fixed and portable detectors. Installation of a fixed gas detector can benefit a larger space such as cellars or plant rooms to provide continuous area and staff protection 24 hours a day. However, for worker safety in and around cylinder storage area and in spaces designated as a confined space, a portable detector can be more suited. This is especially true for pubs and beverage dispensing outlets for the safety of workers and those who are unfamiliar in the environment such as delivery drivers, sales teams or equipment technicians. The portable unit can easily be clipped to clothing and will detect pockets of CO₂using alarms and visual signals, indicating that the user should immediately vacate the area.

For more information about gas detection in drink dispense systems, contact our team.

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Industry Overview: Food and Beverage

The food and beverage (F&B) industry includes all companies involved in processing raw food materials, as well as those packaging and distributing them. This includes fresh, prepared foods as well as packaged foods, and both alcoholic and non-alcoholic beverages.

The food and beverage industry is divided into two major segments, which are the production and the distribution of edible goods. The first group, production, includes the processing of meats and cheeses and the creation of soft drinks, alcoholic beverages, packaged foods, and other modified foods. Any product meant for human consumption, aside from pharmaceuticals, passes through this sector. Production also covers the processing of meats, cheeses and packaged foods, dairy and alcoholic beverages. The production sector excludes foods and fresh produce that are directly produced via farming, as these fall under agriculture.

The manufacture and processing of food and beverages create substantial risks of fire and toxic gas exposure. Many gases are used for baking, processing and refrigerating foods. These gases can be highly hazardous – either toxic, flammable, or both.

Gas Hazards

Food Processing

Secondary food processing methods includes fermentation, heating, chilling, dehydration or cooking of some kind. Many types of commercial food processing consist of cooking, especially industrial steam boilers. Steam boilers are usually gas-fired (natural gas or LPG) or use a combination of gas and fuel oil. For gas-fired steam boilers, natural gas consists mainly of methane (CH₄), a highly combustible gas, lighter than air, which is piped directly into boilers. In contrast, LPG consists mainly of propane (C₃H₈), and usually requires an on-site fuel storage tank. Whenever flammable gases are used on site, forced mechanical ventilation must be included in storage areas, in case of leakage. Such ventilation is usually triggered by gas detectors that are installed near boilers and in storage rooms.

Chemical Disinfection

The F&B industry takes hygiene very seriously, as the slightest contamination of surfaces and equipment can provide an ideal breeding ground for all kinds of germs. The F&B sector therefore demands rigorous cleaning and disinfection, which must meet industry standards.

There are three methods of disinfection commonly used in F&B: thermal, radiation and chemical. Chemical disinfection with chlorine-based compounds is by far the most common and effective way to disinfect equipment or other surfaces. This is because chlorine-based compounds are inexpensive, fast acting and effective against a variety of microorganisms. Several different chlorine compounds are commonly used, of which include hypochlorite, organic and inorganic chloramines, and chlorine dioxide. Sodium hypochlorite solution (NaOCl) is stored in tanks while chlorine dioxide (ClO₂) gas is usually generated on site.

In any combination, chlorine compounds are hazardous and exposure to high concentrations of chlorine can cause severe health issues. Chlorine gases are usually stored on site and a gas detection system should be installed, with a relay output to trigger ventilation fans once a high level of chlorine is detected.

Food Packaging

Food packaging serves many purposes; it allows food to be transported and stored safely, protects food, indicates portion sizes and provides information about the product. To keep food items safe for a long time, it is necessary to remove oxygen from the container because otherwise, oxidation will occur when the food comes into contact with oxygen. The presence of oxygen also promotes bacterial growth, which is harmful when consumed. However, if the package is flushed with nitrogen, the shelf life of packaged food can be extended.

Packagers often use nitrogen (N₂) flushing methods for preserving and storing their products. Nitrogen is a non-reactive gas, non-odorous and non-toxic. It prevents oxidation of fresh food with sugars or fats, stops the growth of dangerous bacteria and inhibits spoilage. Lastly, it prevents packages from collapsing by creating a pressurized atmosphere. Nitrogen can be generated on site using generators or delivered in cylinders. Gas generators are cost effective and provide an uninterrupted supply of gas. Nitrogen is an asphyxiant, capable of displacing oxygen in air. Because it has no smell and is non-toxic, workers may not become aware of low oxygen conditions before it is too late.

Oxygen levels below 19% will cause dizziness and loss of consciousness. To prevent this, oxygen content should be monitored with an electrochemical sensor. Installing oxygen detectors in packaging areas ensures the safety of workers and early detection of leaks.

Refrigeration Facilities

Refrigeration facilities in the F&B industry are used to keep food cool for long periods of time. Large-scale food storage facilities often use cooling systems based on ammonia (> 50% NH₃), as it is efficient and economical. However, ammonia is both toxic and flammable; it is also lighter than air and fills up enclosed spaces rapidly. Ammonia can become flammable if released in an enclosed space where a source of ignition is present, or if a vessel of anhydrous ammonia is exposed to fire.

Ammonia is detected with electro-chemical (toxic) and catalytic (flammable) sensor technology. Portable detection, including single- or multi-gas detectors, can monitor instantaneous and TWA exposure to toxic levels of NH3. Multi-gas personal monitors have been shown to improve workers’ safety where a low-range ppm for routine system surveys and flammable range is used during system maintenance. Fixed detection systems include a combination of toxic- and flammable-level detectors connected to local control panels – these are usually supplied as part of a cooling system. Fixed systems can also be used for process over-rides and ventilation control.

Brewing and Drinks Industry

The risk involved in the manufacture of alcohol involves sizable manufacturing equipment which can be potentially harmful, both to operate and because of the fumes and vapours that can be emitted into the atmosphere and subsequently impact the environment. Ethanol is the main combustible hazard found within distilleries and breweries is the fumes and vapours produced by ethanol. With the capacity to be emitted from leaks in tanks, casks, transfer pumps, pipes and flexible hoses, ethanol vapour is a very real fire and explosion hazard faced by those in the distillery industry. Once the gas and vapour is released into the atmosphere, it can quickly build and pose a danger to the health of workers. It is worth noting here however, that the concentration required to cause harm to workers’ health has to be very high. With this in mind, the more significant risk from ethanol in the air is that of explosion. This fact reinforces the importance of gas detection equipment to recognise and remedy any leaks straight away, so as to avoid disastrous consequences.

Packaging, Transport and Dispensing

Once wine is bottled and beer is packaged, they must be delivered to the relevant outlets. This commonly includes distribution companies, warehousing and in the case of breweries, draymen. Beer and soft drinks use carbon dioxide or a mix of carbon dioxide and nitrogen as a way of delivering a beverage to the ‘tap’. These gases also give beer a longer-lasting head and improve the quality and taste.

Even when the beverage is ready to deliver, gas-related hazards remain. Those arise in any activity at premises that contain compressed gas cylinders, due to the risk of increased carbon dioxide levels or depleted oxygen levels (due to high levels of nitrogen). Carbon dioxide (CO₂) occurs naturally in the atmosphere (0.04%). CO₂  is colourless and odourless, heavier than air and if it escapes, will tend to sink to the floor. CO₂ collects in cellars and at the bottom of containers and confined spaces such as tanks and silos. CO₂  is generated in large amounts during fermentation. It is also injected into beverages during carbonation.

To find out more on the gas hazards in food and beverage production visit our industry page for more information.

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The importance of Gas Detection in the Water and Wastewater Industry

Water is vital to our daily lives, both for personal and domestic use and industrial/commercial applications. Whether a facility focuses on the production of clean, potable water or treating effluent, Crowcon is proud to serve a wide variety of water industry clients, providing gas detection equipment that keeps workers safe around the world.

Gas Hazards

Apart from common gas hazards known in the industry; methane, hydrogen sulphide, and oxygen, there are bi-product gas hazards and cleaning material gas hazards that occur from purifying chemicals such as ammonia, chlorine, chlorine dioxide or ozone that are used in the decontamination of the waste and effluent water, or to remove microbes from clean water. There is great potential for many toxic or explosive gases to exist as a result of the chemicals used in the water industry. And added to these are chemicals that may be spilled or dumped into the waste system from industry, farming or building work.

Safety Considerations 

Confined Space Entry

The pipelines used to transport water require regular cleaning and safety checks; during these operations, portable multi-gas monitors are used to protect the workforce. Pre-entry checks must be completed prior to entering any confined space and commonly O₂, CO, H₂S and CH₄ are monitored. Confined spaces are small, so portable monitors must be compact and unobtrusive for the user, yet able to withstand the wet and dirty environments in which they must perform. Clear and prompt indication of any increase in gas monitored (or any decrease for oxygen) is of paramount importance – loud and bright alarms are effective in raising the alarm to the user.

Risk assessment

Risk assessment is critical, as you need to be aware of the environment that you are entering and thus working in. Therefore, understanding the applications and identifying the risks regarding all safety aspects. Focusing on gas monitoring, as part of the risk assessment, you need to be clear on what gases may be present. 

Fit for purpose

There is a variety of applications within the water treatment process, giving the need to monitor multiple gases, including carbon dioxide, hydrogen sulphide, chlorine, methane, oxygen, ozone and chlorine dioxide. Gas detectors are available for single or multiple gas monitoring, making them practical for different applications as well as making sure that, if conditions change (such as sludge is stirred up, causing a sudden increase in hydrogen sulphide and flammable gas levels), the worker is still protected. 

Legislation  

European Commission Directive 2017/164 issued in January 2017, established a new list of indicative occupational exposure limit values (IOELVs). IOELV are health-based, non-binding values, derived from the most recent scientific data available and considering the availability of reliable measurement techniques. The list includes carbon monoxide, nitrogen monoxide, nitrogen dioxide, sulphur dioxide, hydrogen cyanide, manganese, diacetyl and many other chemicals. The list is based on Council Directive 98/24/EC that considers the protection of the health and safety of workers from the risks related to chemical agents in the workplace. For any chemical agent for which an IOELV has been set at Union level, Member States are required to establish a national occupational exposure limit value. They also are required to take into account the Union limit value, determining the nature of the national limit value in accordance with national legislation and practice. Member States will be able to benefit from a transitional period ending at the latest on 21 August 2023. 

The Health and Safety Executive (HSE) state that each year several workers will suffer from at least one episode of work-related illness. Although, most illnesses are relatively mild cases of gastroenteritis, there is also a risk for potentially fatal diseases, such as leptospirosis (Weil’s disease) and hepatitis. Even though these are reported to the HSE, there could be significant under-reporting as there is often failure to recognise the link between illness and work. 

Under domestic law of the Health and Safety at Work etc Act 1974, employers are responsible for ensuring the safety of their employees and others. This responsibility is reinforced by regulations.

The Confined Spaces Regulations 1997 applies where the assessment identifies risks of serious injury from work in confined spaces. These regulations contain the following key duties:

Avoid entry to confined spaces, e.g., by doing the work from the outside.
If entry to a confined space is unavoidable, follow a safe system of work.
Put in place adequate emergency arrangements before the work start.

The Management of Health and Safety at Work Regulations 1999 requires employers and self-employed people to carry out a suitable and sufficient assessment of the risks for all work activities for the purpose of deciding what measures are necessary for safety. For work in confined spaces this means identifying the hazards present, assessing the risks and determining what precautions to take.

Our solutions

Elimination of these gas hazards is virtually impossible, so permanent workers and contractors must depend on reliable gas detection equipment to protect them. Gas detection can be provided in both fixed and portable forms. Our portable gas detectors protect against a wide range of gas hazards, these include T4x, Clip SGD, Gasman, Tetra 3, Gas-Pro, T4 and Detective+. Our fixed gas detectors are used in many applications where reliability, dependability and lack of false alarms are instrumental to efficient and effective gas detection, these include Xgard, Xgard Bright and IRmax. Combined with a variety of our fixed detectors, our gas detection control panels offer a flexible range of solutions that measure flammable, toxic and oxygen gases, report their presence and activate alarms or associated equipment, for the wastewater industry our panels include  Gasmaster.   

To find out more on the gas hazards in wastewater and water treatment visit our industry page for more information. 

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Construction and Key Gas Challenges

Workers in the construction industry are at risk from a wide variety of hazardous gases including Carbon Monoxide (CO), Chlorine Dioxide (CLO₂), Methane (CH₄), Oxygen (O₂), Hydrogen Sulphide (H₂S) and Volatile Organic Compounds (VOC’s).

Through the use of specific equipment, transport and the undertaking of sector specific activities, construction is a main contributor to the emission of toxic gases into the atmosphere, which also means construction personnel are more at risk of ingestion of these toxic contaminants.

Gas challenges can be found in a variety of applications including building material storage, confined spaces, welding, trenching, land clearing and demolition. Ensuring the protection of workers within the construction industry from the multitude of hazards they may encounter is very important. With a specific focus on safeguarding teams from harm by, or the consumption of, toxic, flammable and poisonous gases.

Gas Challenges

Confined Space Entry

Workers are more at risk from hazardous gases and fumes when they are operating within confined spaces. Those entering these spaces need to be protected from the presence of flammable or/and toxic gases such as Volatile Organic Compounds (ppm VOC), Carbon Monoxide (ppm CO) and Nitrogen Dioxide (ppm NO₂). Undertaking clearance measurements and pre-entry safety checks are paramount to ensure safety before a worker enters the space. Whilst in confined spaces gas detection equipment must be worn ongoingly in case of environmental shifts which make the space no longer safe to work in, due to a leak for example, and evacuation is needed.

Trenching and Shoring

During excavation works, such as trenching and shoring, construction workers are at risk of inhaling harmful gases generated by degradable materials present in certain ground types. If undetected, as well as posing risks to the construction workforce, they can also migrate through subsoil and cracks into the completed building and harm housing residents. Trenched areas can also have reduced oxygen levels, as well as contain toxic gases and chemicals. In these cases atmospheric testing should be performed in excavations that exceed four feet. There is also the risk of hitting utility lines when digging which can cause natural gas leaks and lead to worker fatalities.

Building Material Storage

Many of the materials used within construction can release toxic compounds (VOC’s). These can form in a variety of states (solid or liquid) and come from materials such as adhesives, natural and plywood’s, paint, and building partitions. Pollutants include phenol, acetaldehyde and formaldehyde. When ingested, workers can suffer from nausea, headaches, asthma, cancer and even death. VOCs are specifically dangerous when consumed within confined spaces, due to the risk of asphyxiation or explosion.

Welding and Cutting

Gases are produced during the welding and cutting process, including carbon dioxide from the decomposition of fluxes, carbon monoxide from the breakdown of carbon dioxide shielding gas in arc welding, as well as ozone, nitrogen oxides, hydrogen chloride and phosgene from other processes. Fumes are created when a metal is heated above its boiling point and then its vapours condense into fine particles, known as solid particulates. These fumes are obviously a hazard for those working in the sector and illustrate the importance of reliable gas detection equipment to reduce exposure.

Health and Safety Standards

Organisations working in the construction sector can prove their credibility and safety operationally by gaining ISO certification. ISO (International Organisation for Standardisation) certification is split across multiple different certificates, all of which recognise varying elements of safety, efficiency and quality within an organisation. Standards cover best practice across safety, healthcare, transportation, environmental management and family.

Although not a legal requirement, ISO standards are widely recognised as making the construction industry a safer sector by establishing global design and manufacturing definitions for almost all processes. They outline specifications for best practice and safety requirements within the construction industry from the ground up.

In the UK, other recognised safety certifications include the NEBOSH, IOSH and CIOB courses which all offer varied health and safety training for those in the sector to further their understanding of working safely in their given field. 

To find out more on the gas challenges in construction visit our industry page for more information.

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Industry Overview: Battery Power

Batteries are effective at reducing power outages since they can also store excess traditional grid energy. The energy stored within batteries can be released whenever a large volume of power is needed, such as during a power failure at a data centre to prevent data being lost, or as a back-up power supply to a hospital or military application to ensure the continuity of vital services. Large scale batteries can also be used to plug short-term gaps in demand from the grid. These battery compositions can also be used in smaller sizes to power electric cars and may be further scaled down to power commercial products, such as phones, tablets, laptops, speakers and – of course – personal gas detectors.

Applications include battery storage, transportation and welding and can be segregated into four main categories: Chemical – e.g., ammonia, hydrogen, methanol and synthetic fuel, electrochemical – lead acid, lithium ion, Na-Cd, Na-ion, electrical – supercapacitors, superconductive magnetic storage and Mechanical – compressed air, pumped hydro, gravity.

Gas Hazards

Li-ion battery fires

A major concern arises when static electricity or a faulty charger damages the battery protection circuit. This damage can result in fusing the solid-state switches into an ON position, without the user knowing. A battery with a faulty protection circuit may function normally, however, may not provide protection from short circuit. A gas detection system can establish if there is a fault and may be used in a feedback loop to shut off power, seal the space and release an inert gas (such as nitrogen) into the area to prevent any fire or explosion.

Leakage of toxic gases prior to thermal runaway

Thermal runaway of lithium-metal and lithium-ion cells has resulted in several fires. With research showing that fires fuelled by flammable gases are vented from the batteries during thermal runaway. The electrolyte in a lithium-ion battery is flammable and generally contains lithium hexafluorophosphate (LiPF6) or other Li-salts containing fluorine. In the event of overheating, the electrolyte will evaporate and eventually be vented out from the battery cells. Researchers have found that commercial lithium-ion batteries can emit considerable amounts of hydrogen fluoride (HF) during a fire, and that emission rates vary for different types of battery and state of-charge (SOC) levels. Hydrogen fluoride can penetrate skin to affect deep skin tissue and even bone and blood. Even with minimal exposure, pain and symptoms may not present for several hours, by which time damage is extreme.

Hydrogen and explosion risk

With hydrogen fuel cells gaining popularity as alternatives to fossil fuel, it is important to be aware of the dangers of hydrogen. Like all fuels, hydrogen is highly flammable and if it leaks there is real risk of fire. Traditional lead acid batteries produce hydrogen when they are being charged. These batteries are normally charged together, sometimes in the same room or area, which can generate an explosion risk, especially if the room is not properly ventilated. Most hydrogen applications cannot use odorants for safety, as hydrogen disperses faster than odorants do. There are applicable safety standards for hydrogen fuelling stations, whereby appropriate protective gear is required for all workers. This includes personal detectors, capable of detecting ppm level hydrogen as well as %LEL level. The default alarm levels are set at 20% and 40% LEL which is 4% volume, but some applications may wish to have a custom PPM range and alarm levels to pick up hydrogen accumulations quickly.

To find out more on the dangers of gas hazards in battery power visit our industry page for more information.

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The Dangers of Gas in Farming and Agriculture

Farming and agriculture is a colossal industry the world over, providing more than 44 million jobs in the EU and making up over 10% of total US employment.

With a wide range of processes involved in this sector, there are bound to be hazards that must be considered. These include gas hazards from the likes of methane, hydrogen sulphide, ammonia, carbon dioxide and nitrous oxide.

Methane is a colourless, odourless gas which can have harmful effects on humans resulting in slurred speech, vision problems, memory loss, nausea and in extreme cases can impact breathing and heartrate, potentially leading to unconsciousness and even death. In agricultural environments, it is created through anaerobic digestion of organic material, such as manure. The amount of methane generated is exacerbated in areas which are poorly ventilated or high in temperature, and in areas with particular lack of airflow, the gas can build up, become trapped and cause explosions.

Carbon dioxide (CO₂) is a gas which is naturally produced in the atmosphere, levels of which can be heightened by agricultural processes. CO₂ can be emitted by a range of farming process including crop and livestock production and is also emitted by some equipment which is used in agricultural applications. Storage spaces used for waste and grain and sealed silos are of particular concern due to the capacity for CO₂ to build up and displace oxygen, increasing suffocation risk for both animals and humans alike.

Similarly, to methane, hydrogen sulphide comes from the anaerobic decomposition of organic material and can also be found in a range of agricultural processes relating to the production and consumption of biogas. H₂S prevents oxygen from being carried to our vital organs and areas where it builds up often have reduced oxygen concentrations, furthering the risk of asphyxiation where H₂S levels are high. Whilst it could be considered easier to detect due its distinct ‘rotten egg’ smell, the intensity of the smell actually decreases at higher concentrations and prolonged exposure. At high levels, H₂S can cause severe irritation of, and fluid build-up in the lungs and impact the nervous system.

Ammonia (NH₃) is a gas found in animal waste which is often then spread and emitted further through slurry spreading on agricultural land. As with many of the gases covered, the impact of ammonia is heightened when there is a lack of ventilation. It is harmful to the wellbeing of both livestock and humans, causing respiratory diseases in animals whilst high levels can lead to burns and swelling of the airways and lung damage in humans and can be fatal.

Nitrogen oxide (NO₂) is another gas to be aware of in the agriculture and farming industry. It is present in synthetic fertilisers which are often used in more intensive farming practices to ensure greater crop yields. The potential negative health impacts of NO₂in humans include reduced lung function, internal bleeding, and ongoing respiratory problems.

Workers in this industry are frequently on the move, and for this specific purpose Crowcon offers a wide range of fixed and portable gas detectors to keep workers safe. Crowcon’s portable range comprises T4, Gas-Pro, Clip SGD and Gasman all of which offer reliable, transportable detection capacities for a variety of gases. Our fixed gas detectors are used where reliability, dependability and lack of false alarms are instrumental to efficient and effective protection of assets and areas, and include the Xgard and Xgard Bright. Combined with a variety of our fixed detectors, our gas detection control panels offer a flexible range of solutions that measure flammable, toxic and oxygen gases, report their presence and activate alarms or associated equipment, for the farming and agriculture industry we often recommend our Gasmaster, Vortex and Addressable Controllers panels.

To find out more on the gas hazards in farming and agriculture visit our industry page for more information.

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